Overview
Wacker H18 Nanosilica is a high-performance fumed silica produced by Wacker Chemie AG, a leading German chemical manufacturer. This hydrophobic variant undergoes surface treatment to enhance compatibility with non-polar systems, making it ideal for silicone-based applications. Its primary function is to improve mechanical properties like tensile strength and tear resistance in elastomers while acting as a rheology modifier in liquids. The product is manufactured through flame hydrolysis of silicon tetrachloride, resulting in ultra-fine particles with a chain-like aggregate structure. As a nano-material, it provides exceptional reinforcement at low loading levels, typically between 5–15% in formulations. Industrial users value its predictable performance and batch-to-batch consistency.
Physical and Chemical Properties
With a BET surface area of 180±20 m²/g, Wacker H18 offers substantial interface activity that contributes to its thickening and reinforcing effects. The hydrophobic surface modification—typically with dimethyldichlorosilane—reduces moisture absorption to below 1% (at 50% RH), preventing clumping and ensuring free-flowing powder characteristics. Particle size distribution ranges between 7–40 nm in primary diameter, forming aggregates of 100–300 nm. The material exhibits pH neutrality (5.0–7.5 in 4% aqueous dispersion) and low ionic impurity content (<500 ppm chloride). Its thermal stability exceeds 600°C, making it suitable for high-temperature processing in silicone rubber vulcanization.
Main Applications
In silicone rubber formulations, H18 nanosilica significantly enhances mechanical properties, enabling production of high-performance gaskets, seals, and medical devices. It increases Shore hardness without compromising elasticity and improves compression set resistance by up to 30% compared to unfilled silicones. The product serves as an anti-settling agent in adhesives and sealants, maintaining uniform filler distribution during storage. Coatings manufacturers utilize it for sag control in vertical applications and to impart scratch resistance. Specialty applications include use in defoamer concentrates, where it stabilizes oil droplets, and in thermally conductive silicone pads for electronics cooling systems.
Safety and Storage
As a fine powder, Wacker H18 requires careful handling to prevent dust generation. NIOSH-approved dust masks (N95 or equivalent) are recommended during bulk transfer operations. The material is classified as a nuisance dust with a TLV of 2 mg/m³ for respirable particles under OSHA guidelines. Storage should maintain relative humidity below 65% to preserve hydrophobicity. Original packaging—typically multi-layer kraft paper bags with polyethylene liners—provides 12-month stability when unopened. Opened containers should be resealed with nitrogen purging if long-term storage is needed. Spills should be cleaned with vacuum systems rather than brooms to avoid airborne dispersion.
B2B Procurement Guide
Industrial buyers should specify the H18 designation clearly, as Wacker produces multiple silica grades with differing surface treatments. Key procurement considerations include verifying certificates of analysis for surface area, loss on drying (max 1.5%), and sieve residue (typically <0.05% on 45μm sieve). Bulk purchases (palletized 10–20 kg bags) typically offer 10–15% cost savings versus small-quantity orders. Just-in-time delivery is preferable to prolonged warehouse storage. Alternative supply options include HDK® H18 from Wacker’s competitors, though formulation revalidation may be necessary due to differences in surface chemistry and aggregate structure.
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