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Vinyl Caprolactam

Updated: 2026-07-15

Overview

Vinyl Caprolactam (VCAP) is a reactive monomer derived from caprolactam, featuring a vinyl group that enables polymerization. It is widely used in industrial and consumer applications due to its ability to enhance adhesion, flexibility, and durability in polymer formulations. First synthesized in the mid-20th century, VCAP has become a key ingredient in adhesives, coatings, and personal care products. Its compatibility with various solvents and other monomers makes it a versatile choice for formulators seeking to improve product performance.

Physical and Chemical Properties

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VCAP is a colorless to pale yellow liquid with a mild odor. It has a molecular weight of 139.20 g/mol and a density of 0.99 g/cm³. The compound is soluble in water and common organic solvents like ethanol and acetone, facilitating its use in diverse formulations. Its boiling point is 94-96°C at reduced pressure (1 mmHg), and it polymerizes readily under heat or in the presence of initiators. The vinyl group in VCAP allows for copolymerization with other monomers, enabling tailored material properties for specific applications.

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Main Applications

VCAP is a critical component in adhesives and coatings, where it improves adhesion to substrates and enhances film flexibility. In the personal care industry, it is used in hair sprays and styling products due to its film-forming properties. Additionally, VCAP finds use in printing inks, where it contributes to durability and scratch resistance. In pharmaceuticals, it serves as a solubilizing agent for poorly water-soluble drugs, leveraging its amphiphilic nature.

Safety and Storage

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VCAP is classified as an irritant and can cause skin and eye irritation upon contact. Proper handling includes wearing gloves, goggles, and ensuring adequate ventilation in workspaces. Storage should be in tightly sealed containers away from heat and light. Polymerization inhibitors are often added to commercial VCAP to prevent unintended reactions during storage. Users should monitor inhibitor levels and replenish them if necessary to maintain stability.

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B2B Procurement Guide

When procuring VCAP, buyers should prioritize suppliers who provide detailed certificates of analysis (CoA) to verify purity and inhibitor content. Bulk purchases (e.g., drum or tanker quantities) typically offer cost savings but require proper storage facilities. For specialized applications, custom formulations with co-monomers or additives may be available. Buyers should communicate their performance requirements to suppliers to ensure optimal product selection.

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