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Tributyltin fluoride

Updated: 2026-07-21

Overview

Tributyltin Fluoride (TBTF) is an organotin compound primarily used for its biocidal properties. It belongs to the tributyltin family, which has been historically significant in marine antifouling applications. Due to its environmental and health risks, its use is now heavily regulated or banned in many countries. TBTF is synthesized through the reaction of tributyltin chloride with hydrogen fluoride. Despite its declining use, it remains relevant in specific industrial and research contexts where alternatives are not feasible.

Physical and Chemical Properties

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Tributyltin Fluoride appears as a white to off-white crystalline solid with a molecular weight of 309.04 g/mol. It is soluble in organic solvents like ethanol and acetone but exhibits negligible solubility in water. The compound is stable under normal conditions but may decompose upon exposure to strong acids or oxidizing agents. Its density is approximately 1.20 g/cm³, and it exhibits high toxicity to aquatic organisms. The fluorine atom in TBTF enhances its biocidal activity compared to other tributyltin derivatives, making it effective in low concentrations.

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Main Applications

Historically, TBTF was widely used in antifouling paints for ships and marine structures to prevent the growth of algae, barnacles, and other organisms. It also served as a wood preservative and industrial biocide in cooling towers and paper mills. Today, its applications are limited due to environmental regulations. However, it is still employed in niche industrial processes and research, particularly where alternative biocides are ineffective. Some countries permit controlled use in non-marine applications under strict guidelines.

Safety and Storage

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Tributyltin Fluoride is highly toxic to humans and the environment. Exposure can occur via inhalation, ingestion, or skin contact, leading to severe health effects such as neurological damage and organ failure. Proper personal protective equipment (PPE), including gloves, goggles, and respirators, is mandatory during handling. Storage requires a cool, dry, and well-ventilated area, away from moisture and oxidizing agents. Containers must be tightly sealed and labeled according to hazardous material regulations. Spills should be contained and reported immediately to prevent environmental contamination.

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B2B Procurement Guide

When procuring TBTF, B2B buyers must prioritize regulatory compliance, as many regions restrict or ban its use. Verify supplier certifications and ensure the product meets purity specifications for intended applications. Documentation, including Safety Data Sheets (SDS) and legal permits, should be thoroughly reviewed. Pricing varies based on purity and quantity, typically ranging from $50 to $100 per kg. Due to its declining use, sourcing may require specialized chemical distributors. Buyers should also explore eco-friendly alternatives to mitigate legal and environmental risks.

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