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Titanium Chloride

Updated: 2026-07-20

Overview

Titanium chloride, specifically titanium tetrachloride (TiCl4), is a key inorganic compound in industrial chemistry. It is widely recognized for its role as a catalyst in Ziegler-Natta polymerization, which produces polyethylene and polypropylene. The compound is also essential in the production of titanium metal and its alloys. Due to its high reactivity, titanium chloride must be handled with care, especially in moist environments where it releases hydrochloric acid fumes. Its applications extend to organic synthesis, where it serves as a Lewis acid catalyst.

Physical and Chemical Properties

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Titanium chloride is a colorless to pale yellow liquid at room temperature, with a pungent odor. It has a high density and fumes upon contact with air due to hydrolysis. The compound reacts violently with water, producing heat and corrosive hydrochloric acid. Its solubility in organic solvents like ethanol and ether makes it useful in various chemical reactions. The boiling point of 136.4°C and low melting point of -24.1°C indicate its volatility, requiring careful storage and handling.

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Main Applications

The primary use of titanium chloride is as a catalyst in the production of plastics, particularly polyolefins. It is also employed in the manufacture of titanium dioxide pigments, which are used in paints, coatings, and plastics. In the aerospace and automotive industries, titanium chloride is a precursor for titanium metal and alloys, known for their strength and corrosion resistance. Additionally, it finds applications in organic synthesis, such as the Friedel-Crafts acylation reactions.

Safety and Storage

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Titanium chloride is highly corrosive and poses significant health risks, including severe burns and respiratory irritation. Proper personal protective equipment (PPE), such as gloves, goggles, and respirators, is essential when handling this chemical. Storage must be in tightly sealed containers, away from moisture and incompatible materials like water and alcohols. Facilities should have adequate ventilation and spill containment measures to mitigate accidental releases.

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B2B Procurement Guide

When procuring titanium chloride, prioritize suppliers who provide detailed material safety data sheets (MSDS) and comply with international safety standards. Bulk purchases often offer cost advantages, but ensure proper storage facilities are available. Verify the purity grade required for your application, as industrial and reagent grades differ significantly. Establish clear logistics protocols to prevent exposure during transportation, especially for international shipments.

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