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Thulium(III) fluoride

Updated: 2026-08-04

Overview

Thulium(III) Fluoride (TmF3) is a rare-earth fluoride compound composed of thulium and fluorine. It is primarily utilized in specialized industrial applications due to its unique optical and electronic properties. As a member of the lanthanide series, thulium contributes to the compound's distinct characteristics, making it valuable in high-tech industries. Thulium(III) Fluoride is synthesized through reactions between thulium oxide (Tm2O3) and hydrofluoric acid (HF). The resulting compound is a white, crystalline powder that is stable under normal conditions but requires careful handling due to its reactivity with moisture and acids.

Physical and Chemical Properties

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Thulium(III) Fluoride exhibits several notable physical and chemical properties. It has a high melting point of approximately 1150°C and a density of 7.1 g/cm³, reflecting its stability under high-temperature conditions. The compound is insoluble in water, which makes it suitable for applications requiring moisture resistance. Its optical properties are particularly significant; TmF3 is transparent in the infrared region, making it useful for coatings and lenses in optical devices. Additionally, its thermal stability and low solubility contribute to its reliability in electronic and laser applications.

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Main Applications

Thulium(III) Fluoride is widely used in the optical industry for coatings and lenses, especially in infrared applications. Its transparency in the infrared spectrum makes it ideal for laser systems and optical filters. The compound is also employed in the production of specialty glasses and ceramics. In the electronics industry, TmF3 serves as a dopant in optical fibers and other electronic components, enhancing their performance. Its thermal stability and resistance to degradation under high-energy conditions make it a preferred material for advanced technological applications.

Safety and Storage

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Handling Thulium(III) Fluoride requires adherence to strict safety protocols. The compound should be stored in a cool, dry environment, away from moisture and acids, to prevent decomposition. Personal protective equipment (PPE), including gloves and safety goggles, is essential to avoid skin contact and inhalation. In case of exposure, immediate medical attention is recommended. The compound is not highly toxic but can cause irritation upon contact with skin or eyes. Proper ventilation is advised when working with TmF3 to minimize the risk of airborne particles.

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B2B Procurement Guide

When procuring Thulium(III) Fluoride, B2B buyers should prioritize suppliers with a proven track record in rare-earth compounds. Key factors to consider include purity levels (typically 99.9% or higher), packaging quality to prevent moisture exposure, and compliance with international safety standards. Requesting material safety data sheets (MSDS) and certificates of analysis (CoA) is crucial to ensure product quality. Prices vary based on purity and quantity, with bulk purchases often offering cost advantages. Establishing long-term relationships with reliable suppliers can ensure consistent quality and timely delivery.

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