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Tetrachloride

Updated: 2026-08-30

Overview

Carbon tetrachloride (CCl4) is a synthetic organic compound historically valued for its solvent properties and non-flammability. It was widely used in fire extinguishers, dry cleaning, and refrigeration until its toxicity and environmental hazards were recognized. Today, its use is heavily restricted under international agreements like the Montreal Protocol due to its ozone-depleting effects. Despite its declining industrial role, carbon tetrachloride remains relevant in niche applications, such as laboratory research and specialized chemical synthesis. Its production and use are strictly regulated, requiring proper handling and disposal to mitigate health and environmental risks.

Physical and Chemical Properties

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Carbon tetrachloride is a dense, colorless liquid with a characteristic sweet odor. It is non-flammable and evaporates easily, forming vapors heavier than air. Its chemical stability and ability to dissolve fats and oils made it a popular solvent in the past. The compound's high toxicity arises from its metabolism into reactive intermediates in the liver, leading to cellular damage. It is also a potent greenhouse gas and contributes to stratospheric ozone depletion. These properties have driven its phase-out in most consumer and industrial applications.

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Main Applications

Historically, carbon tetrachloride was used in fire extinguishers (particularly for electrical fires), as a degreasing agent, and in the production of refrigerants. Its role as a solvent extended to pharmaceuticals and rubber manufacturing. Modern applications are limited to controlled environments, such as analytical chemistry for calibrating instruments or synthesizing chlorofluorocarbons (CFCs) under strict regulations. Some industrial processes still employ it as a feedstock, but alternatives are increasingly favored due to regulatory pressures.

Safety and Storage

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Handling carbon tetrachloride requires stringent safety measures, including fume hoods, gloves, and eye protection. Inhalation or skin absorption can cause severe organ damage, and chronic exposure is linked to cancer. Storage must avoid heat and incompatible materials like alkali metals. Disposal must comply with hazardous waste regulations, often involving incineration with scrubbing to prevent toxic byproducts. Leaks should be contained using inert absorbents, and contaminated areas ventilated thoroughly.

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B2B Procurement Guide

Procuring carbon tetrachloride demands due diligence to ensure regulatory compliance. Buyers should verify suppliers' permits and material safety data sheets (MSDS). Purity grades (e.g., reagent or technical) must align with intended use, with laboratory-grade commanding higher prices. Given its restricted status, buyers may face logistical challenges, including transportation restrictions and end-use certifications. Alternatives like tetrachloroethylene or hydrocarbon solvents should be evaluated where feasible to reduce legal and safety risks.

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