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Sulfonated Tannin

Updated: 2026-07-19

Overview

Industrial sulfonated tannin extract is derived from natural tannins through controlled sulfonation processes, enhancing water solubility and chemical reactivity. Primarily sourced from quebracho, chestnut, or mimosa bark, this modified tannin product serves as an environmentally friendly alternative to synthetic chemicals in various industrial processes. The sulfonation process introduces sulfonic acid groups into the tannin molecules, imparting anionic surfactant properties. This modification makes the product particularly valuable in applications requiring both dispersing and chelating capabilities, bridging the gap between natural materials and synthetic performance chemicals.

Physical and Chemical Properties

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The material exhibits excellent thermal stability, maintaining functionality at temperatures up to 200°C, which is critical for oilfield applications. Its anionic nature provides strong dispersing power for inorganic precipitates, with particular effectiveness against calcium carbonate and sulfate scales. Chemically, sulfonated tannins demonstrate remarkable chelation capacity for polyvalent metal ions (Fe³⁺, Ca²⁺, Mg²⁺), with binding constants comparable to EDTA in certain pH ranges. The degree of sulfonation significantly affects performance, with industrial grades typically containing 2-3 sulfonate groups per tannin molecule.

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Main Applications

In water treatment systems, sulfonated tannin serves as a biodegradable scale inhibitor and dispersant, particularly effective in cooling towers and boiler feedwater systems. Its natural origin makes it preferable for applications requiring environmental compliance. The leather industry utilizes this product as a retanning agent that improves fiber dispersion and dye penetration while reducing chrome usage. In oilfield applications, it functions as a high-temperature thinner for drilling fluids and a shale inhibitor in water-based muds, outperforming many synthetic alternatives in environmentally sensitive areas.

Safety and Storage

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As a modified natural product, sulfonated tannin extract presents low toxicity (LD50 > 2000 mg/kg) but may cause mild respiratory irritation in powder form. Proper PPE including dust masks and gloves is recommended during bulk handling. Storage requires protection from moisture absorption, which can lead to caking and reduced solubility. Industrial packaging typically uses multi-layer kraft paper bags with polyethylene liners, with recommended shelf life of 24 months under proper conditions (relative humidity <60%, temperature <30°C).

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B2B Procurement Guide

Key specifications to evaluate include sulfonation degree (measured by sulfur content, ideally 8-12%), tannin purity (minimum 65%), and solubility (should fully dissolve in water at 25°C within 30 minutes). Bulk procurement should consider regional supply chains - South American suppliers often offer quebracho-based products, while Asian manufacturers typically process acacia or chestnut tannins. For specialty applications, request test reports on specific performance parameters such as calcium carbonate dispersion efficiency or high-temperature stability.

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