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Updated: 2026-08-07

Overview

Sodium Hydroxide (NaOH) is one of the most widely used industrial chemicals, known for its strong alkaline properties. It is produced through the electrolysis of sodium chloride (salt) solution in a process called the chloralkali process. The compound is essential in various industries due to its reactivity and ability to neutralize acids. In its pure form, Sodium Hydroxide is a white, crystalline solid that absorbs moisture from the air (hygroscopic). It is highly soluble in water, releasing significant heat upon dissolution. Due to its corrosive nature, handling requires strict safety protocols.

Physical and Chemical Properties

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Sodium Hydroxide exhibits several notable physical and chemical properties. It has a high melting point of 318°C and a boiling point of 1,388°C, making it stable under high temperatures. The compound is highly soluble in water, ethanol, and methanol, with its aqueous solutions being strongly alkaline. Chemically, NaOH is a strong base that reacts vigorously with acids to form salts and water (neutralization reactions). It also reacts with metals like aluminum to produce hydrogen gas, and with fats/oils in saponification reactions, making it crucial in soap manufacturing. Its hygroscopic nature necessitates careful storage to prevent absorption of atmospheric moisture.

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Main Applications

Sodium Hydroxide is indispensable in numerous industrial processes. In the chemical industry, it is used to manufacture sodium salts, detergents, and synthetic fibers. The paper industry relies on NaOH for pulping and bleaching wood to produce paper. Water treatment plants use it to adjust pH levels and remove heavy metals. In food processing, it aids in peeling fruits and vegetables, and in preparing products like hominy and pretzels. Additionally, NaOH is vital in biodiesel production and petroleum refining, highlighting its versatility across sectors.

Safety and Storage

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Due to its highly corrosive nature, Sodium Hydroxide requires stringent safety measures. Direct contact can cause severe chemical burns to skin and eyes, and inhalation of dust or mist may lead to respiratory irritation. Proper personal protective equipment (PPE), including gloves, goggles, and respirators, is mandatory during handling. Storage should be in cool, dry, well-ventilated areas, away from acids and moisture. Containers must be tightly sealed to prevent absorption of CO₂ from the air, which can reduce potency. Spills should be neutralized with weak acids like vinegar and cleaned up immediately to prevent damage to surfaces and injury to personnel.

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B2B Procurement Guide

When procuring Sodium Hydroxide in bulk, businesses should prioritize supplier reliability and product quality. Verify that suppliers comply with international standards such as ISO or REACH. Request certificates of analysis (CoA) to confirm purity levels, typically ranging from 98-99% for industrial-grade NaOH. Consider transportation logistics, as NaOH is often shipped in solid flakes, pellets, or liquid form (aqueous solution). Ensure packaging is corrosion-resistant, such as polyethylene-lined drums or tanker trucks for liquids. Pricing varies based on market demand, region, and order volume, with discounts commonly available for long-term contracts or large purchases.

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