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Sodium Hydroxide

Updated: 2026-07-25

Overview

Sodium Hydroxide (NaOH), also known as caustic soda, is one of the most widely used industrial chemicals. It is a strong alkaline compound that plays a critical role in various manufacturing processes, from petroleum refining to food production. First produced commercially in the late 19th century, sodium hydroxide is now primarily manufactured through the chloralkali process, which involves the electrolysis of sodium chloride (salt) solutions. Its versatility and reactivity make it indispensable across multiple industries.

Physical and Chemical Properties

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Sodium hydroxide is a white, odorless solid at room temperature, available in pellets, flakes, or aqueous solutions. It is highly hygroscopic, absorbing moisture from the air, which can cause it to dissolve in its own water of absorption. The compound exhibits strong alkaline properties, with a pH of 14 in 1M aqueous solution. It reacts exothermically with water and acids, generating significant heat. NaOH also reacts with aluminum and zinc to produce hydrogen gas, a potentially hazardous combination.

Main Applications

In the chemical industry, sodium hydroxide is used for pH regulation, neutralization reactions, and as a catalyst in organic synthesis. It's essential in manufacturing soaps, detergents, and various organic and inorganic chemicals. The pulp and paper industry consumes large quantities of NaOH for wood pulping and bleaching processes. In water treatment, it adjusts pH levels and removes heavy metals. Other applications include food processing (for peeling fruits and vegetables), textile production, and petroleum refining.

Safety and Storage

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Sodium hydroxide requires careful handling due to its corrosive nature. Direct contact can cause severe burns to skin and eyes, while inhalation of dust or mists may damage respiratory tissues. Proper storage involves keeping containers tightly sealed in dry, cool areas separate from acids and moisture-sensitive materials. Secondary containment is recommended for liquid solutions. Spill kits with neutralizing agents (such as weak acids) should be readily available in handling areas.

B2B Procurement Guide

When procuring sodium hydroxide industrially, consider the required form (solid flakes/pellets vs. solution concentration), purity grade (industrial, reagent, or food grade), and packaging options (bulk, drums, or bags). Evaluate supplier reliability through certifications like ISO and review their safety data sheets. Transportation costs are significant for aqueous solutions due to water content. Just-in-time delivery may be preferable for users with limited storage capacity.

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