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Sodium Acid

Updated: 2026-08-17

Overview

Sodium dihydrogen phosphate (NaH2PO4) is an inorganic compound classified as a primary acid regulator and buffering agent. It is the monosodium salt of phosphoric acid, widely used across industries due to its ability to control pH levels precisely. As a GRAS (Generally Recognized As Safe) substance, it plays critical roles in food processing, water treatment systems, and pharmaceutical formulations. Its production typically involves the neutralization of phosphoric acid with sodium hydroxide or sodium carbonate under controlled conditions.

Physical and Chemical Properties

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This compound appears as odorless white crystals or powder with a density of 2.36 g/cm³. It exhibits high solubility in water (85g/100ml at 20°C) but remains insoluble in organic solvents like ethanol. The aqueous solution shows acidic properties with pH ~4.5 (1% solution). When heated above 200°C, it decomposes to form sodium polyphosphates. The substance is hygroscopic, requiring careful storage to prevent caking. Its buffering capacity is most effective in pH ranges between 4.0-5.5, making it ideal for biological and chemical systems requiring stable slightly acidic conditions.

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Main Applications

In food processing (E339i), it functions as an acidity regulator in baked goods, cheeses, and beverages. It prevents oxidation and modifies texture in processed meats. The pharmaceutical industry utilizes it in saline solutions and as an excipient in tablet formulations. Industrial applications include water treatment (corrosion inhibition), detergent manufacturing (builder agent), and agricultural fertilizers (phosphorus source). Laboratory uses encompass buffer preparation for biological assays and chemical processes requiring controlled acidic environments.

Safety and Storage

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Classified as non-hazardous, though dust may irritate respiratory tracts. Use NIOSH-approved dust masks and goggles when handling powder forms. Store in original tightly sealed containers at ambient temperature (15-30°C) with relative humidity below 65%. Incompatible with strong bases and oxidizing agents. Spills should be contained with inert absorbents and disposed following local regulations. For large-scale storage, use polyethylene-lined bags or fiber drums with desiccants to prevent moisture absorption and subsequent caking.

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B2B Procurement Guide

Specify required grade (food, pharmaceutical, technical) and purity (typically 98-102%). Food-grade must comply with FCC/EP/USP standards. Industrial grade should meet ISO or ASTM specifications. Verify particle size (powder/granular) and packaging (25kg bags, 1000kg supersacks). Request COA (Certificate of Analysis) for each batch. Consider suppliers with ISO 9001 certification and HACCP compliance for food applications. Bulk shipments require moisture-proof containers with palletization options for logistics efficiency.

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