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R21

Updated: 2026-07-17

Overview

R21, also known as Dichlorofluoromethane or Freon 21, is a chlorofluorocarbon (CFC) refrigerant. It was widely used in air conditioning and refrigeration systems before the implementation of the Montreal Protocol due to its ozone-depleting properties. Despite its phasedown, R21 remains relevant in specific industrial applications where alternatives are not feasible. R21 is valued for its thermodynamic properties, including a moderate boiling point and stability under typical operating conditions. However, its use is now restricted in many countries due to environmental concerns, and alternatives like HFCs and natural refrigerants are preferred.

Physical and Chemical Properties

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R21 is a colorless gas with a slight ethereal odor. It has a molecular weight of 102.92 g/mol and a boiling point of 8.9°C, making it suitable for low-temperature refrigeration applications. The gas is non-flammable and exhibits low toxicity, but prolonged exposure can cause dizziness or asphyxiation in confined spaces. Its density as a liquid is 1.48 g/cm³ at 20°C, and it is slightly soluble in water. R21 is chemically stable under normal conditions but can decompose at high temperatures, releasing toxic gases such as hydrogen chloride and hydrogen fluoride.

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Main Applications

R21 was primarily used as a refrigerant in air conditioning and refrigeration systems, particularly in industrial and commercial settings. Its thermodynamic properties made it effective for medium-temperature cooling applications. Additionally, R21 served as a blowing agent in the production of foam insulation and as a solvent in specialized chemical processes. Due to its ozone-depleting potential, R21 has been largely replaced by more environmentally friendly alternatives. However, it may still be used in legacy systems or in regions where regulations permit its limited application for specific industrial purposes.

Safety and Storage

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Handling R21 requires adherence to safety protocols to minimize health and environmental risks. Workers should use personal protective equipment (PPE), including gloves and goggles, and ensure adequate ventilation to prevent inhalation exposure. Storage should be in cool, dry areas away from heat sources and incompatible materials. Leaks or spills should be addressed immediately using appropriate containment measures. Disposal must comply with local environmental regulations, as improper release can contribute to ozone layer depletion. Always consult safety data sheets (SDS) for detailed handling instructions.

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B2B Procurement Guide

When procuring R21, B2B buyers should verify the purity and CAS number (75-43-4) to ensure product authenticity. Suppliers should provide certificates of analysis and comply with international environmental standards, such as the Montreal Protocol. Pricing varies based on quantity and supplier, with reference prices ranging from $10 to $20 per kg. Buyers should also consider the logistical challenges of transporting refrigerants, including proper labeling and packaging to prevent leaks. Alternative refrigerants should be evaluated for compliance with current regulations and long-term sustainability goals.

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