Overview
Quicklime (calcium oxide) is a fundamental industrial chemical produced by calcining limestone (calcium carbonate) at high temperatures (900-1,200°C). This process drives off carbon dioxide, leaving behind the pure oxide. Historically used since ancient times for construction and mortar, it remains indispensable in modern industries due to its reactivity and alkaline properties. As a bulk chemical commodity, quicklime is typically traded in lump, pebble, or powdered forms. The quality varies based on raw material source and manufacturing process, with industrial-grade material containing 90-95% CaO. Its exothermic reaction with water (slaking) produces hydrated lime (calcium hydroxide), forming the basis for many applications.
Physical and Chemical Properties
Quicklime appears as a white or grayish-white solid with a crystalline structure when pure. It has an exceptionally high melting point (2,572°C) and density (3.34 g/cm³), making it stable under extreme conditions. The material is hygroscopic, readily absorbing moisture from air, which necessitates careful storage. Chemically, CaO is a strong base that reacts violently with water in a highly exothermic process (ΔH = -63.7 kJ/mol). This reaction forms calcium hydroxide and generates significant heat, capable of causing thermal burns. Quicklime also reacts with acids to form salts and can absorb carbon dioxide from air, gradually reverting to calcium carbonate.
Main Applications
In construction, quicklime is essential for producing mortar, plaster, and whitewash through slaking. Modern steelmaking consumes vast quantities as a flux to remove impurities (silica, phosphorus) during refining. The pulp/paper industry uses it in Kraft processes for wood digestion and chemical recovery. Environmental applications include water treatment (pH adjustment, softening) and flue gas desulfurization in power plants. Chemical manufacturing employs quicklime as a precursor for calcium compounds (e.g., carbide, hypochlorite) and in biodiesel production. Agricultural uses include soil pH modification and as a disinfectant in livestock housing.
Safety and Storage
Quicklime poses significant hazards: it is corrosive (pH ~12.5 when wet), causes severe skin/eye burns, and generates heat upon contact with moisture. Workers must wear acid-resistant gloves, goggles, and dust masks. Inhalation of dust irritates respiratory tracts, requiring adequate ventilation or respiratory protection. Storage requires airtight, moisture-proof containers (often polyethylene-lined bags) in dry warehouses. Bulk storage silos should have humidity controls. Never store near acids or organic materials, as reactions may generate heat or flammable hydrogen gas. Firefighting requires dry chemical agents—water application intensifies heat generation.
B2B Procurement Guide
Industrial buyers should prioritize suppliers with ISO certifications and consistent quality control. Key specifications include CaO content (≥90% for most applications), reactivity (measured by slaking rate), and particle size distribution (varies by use case). Packaging options range from 25kg bags to bulk tankers for large-scale consumers. Logistics considerations include moisture protection during transit—humidity-controlled containers are preferable for sea shipments. Regional pricing varies based on limestone availability and energy costs; Chinese exports typically range $80-$120/ton FOB. Negotiate long-term contracts with price adjustment clauses to mitigate market volatility linked to energy prices.
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