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Updated: 2026-08-05

Overview

Sodium hydroxide (NaOH) is a fundamental industrial chemical with a wide range of applications due to its strong alkaline properties. It is produced through the electrolysis of sodium chloride (salt) solution, a process known as the chloralkali process. NaOH is available in various forms, including pellets, flakes, and aqueous solutions. As a highly reactive compound, sodium hydroxide plays a critical role in numerous industrial processes. Its ability to neutralize acids and react with various organic compounds makes it indispensable in chemical synthesis, petroleum refining, and water treatment applications.

Physical and Chemical Properties

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Sodium hydroxide is characterized by its white crystalline appearance and hygroscopic nature, meaning it readily absorbs moisture from the air. It has a high melting point of 318°C and forms a strongly alkaline solution when dissolved in water, with a pH of approximately 14 for concentrated solutions. Chemically, NaOH is highly reactive with acids, forming water and corresponding salts (neutralization). It also reacts with aluminum and zinc to produce hydrogen gas, and with fats in saponification reactions. These properties make it both useful and potentially hazardous, requiring careful handling.

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Main Applications

In the chemical industry, sodium hydroxide is used in the production of various compounds including soaps, detergents, and synthetic fibers. The paper industry relies on NaOH for pulping and bleaching processes, while petroleum refining uses it to remove acidic contaminants from fuels. Water treatment plants utilize sodium hydroxide for pH adjustment and heavy metal precipitation. In food processing, it serves as a peeling agent for fruits and vegetables, and in the production of food additives. Emerging applications include biodiesel production and aluminum ore processing.

Safety and Storage

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Sodium hydroxide requires stringent safety measures due to its corrosive nature. It can cause severe chemical burns to skin and eyes, and inhalation of dust or mists may damage respiratory tissues. Proper PPE including gloves, goggles, and protective clothing is essential when handling this chemical. Storage should be in tightly sealed containers made of materials resistant to strong bases (such as polyethylene or stainless steel). The storage area should be cool, dry, and well-ventilated, separate from acids and other incompatible substances. Spill containment measures should be in place.

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B2B Procurement Guide

When procuring sodium hydroxide commercially, buyers should consider purity requirements (typically 98-99% for industrial use), packaging options (bulk liquid, bags of flakes/pellets), and transportation logistics. Technical grade is suitable for most industrial applications, while food-grade NaOH commands a premium price. Suppliers should provide proper safety documentation including SDS (Safety Data Sheets). Bulk purchases (typically by tanker truck or railcar) offer significant cost savings but require appropriate storage infrastructure. Regional availability and transportation costs significantly impact final pricing.

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