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Potassium Vanadate

Updated: 2026-07-15

Overview

Potassium vanadate (KV) is an inorganic salt composed of potassium and vanadium in a +5 oxidation state. It is primarily used in industrial and laboratory settings due to its catalytic and oxidizing properties. The compound is typically synthesized by reacting vanadium pentoxide with potassium hydroxide or carbonate. As a versatile chemical intermediate, KV finds applications across multiple industries, including chemical manufacturing, metallurgy, and materials science. Its ability to act as a corrosion inhibitor makes it valuable in coatings and surface treatment formulations.

Physical and Chemical Properties

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Potassium vanadate appears as a white to yellowish crystalline powder with a density of 2.8 g/cm³. It decomposes at 520°C rather than melting distinctly. The compound is highly soluble in water, forming alkaline solutions, and shows limited solubility in organic solvents like ethanol. Chemically, KV is a strong oxidizing agent and reacts with reducing substances. It exhibits hygroscopic tendencies, requiring careful storage to prevent moisture absorption. In aqueous solutions, it can form various vanadate species depending on pH, making it useful in redox chemistry applications.

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Main Applications

In industrial catalysis, potassium vanadate serves as an efficient catalyst for oxidation reactions, particularly in organic synthesis and petrochemical processes. It's also employed as a corrosion inhibitor in cooling systems and metal surface treatments, where it forms protective vanadium oxide layers. The compound finds use in ceramic glazes and specialty glass production, where it acts as a colorant and flux. In research laboratories, KV is utilized as a precursor for other vanadium compounds and in electrochemical studies due to its multiple oxidation states.

Safety and Storage

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Potassium vanadate requires careful handling due to its toxicity and corrosive nature. Appropriate personal protective equipment (PPE) including gloves, goggles, and respiratory protection should be used when handling the powder or solutions. Storage should be in cool, dry conditions in tightly sealed containers, preferably made of polyethylene or glass. The compound should be kept away from reducing agents and organic materials. Spills should be contained and cleaned immediately using appropriate procedures to prevent environmental contamination.

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B2B Procurement Guide

Industrial buyers should specify required purity levels (typically 98-99.9% for most applications) and particle size when ordering potassium vanadate. Standard packaging includes 25 kg polyethylene-lined drums or smaller laboratory quantities. Reputable suppliers should provide material safety data sheets (MSDS) and certificates of analysis. Buyers may want to inquire about custom formulations or particle size distributions for specialized applications. Bulk purchases typically offer better pricing, with prices varying based on market conditions and vanadium commodity prices.

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