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Polyricinoleate

Updated: 2026-07-15

Overview

Polyricinoleate, also known as polyglycerol polyricinoleate (PGPR), is a polymer derived from ricinoleic acid, a fatty acid found in castor oil. It is widely used as an emulsifier and viscosity modifier in various industries, particularly in food production and cosmetics. This compound is chemically synthesized through the esterification of ricinoleic acid with polyglycerol, resulting in a non-ionic surfactant with unique properties. Its ability to reduce viscosity and improve texture makes it valuable in chocolate manufacturing and other food applications.

Physical and Chemical Properties

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Polyricinoleate typically appears as a viscous yellow to amber liquid. It is soluble in oils and fats but insoluble in water, making it suitable for oil-based formulations. The polymer lacks a defined melting or boiling point due to its complex structure. Key chemical properties include its role as an emulsifier, which helps stabilize mixtures of immiscible liquids. Its viscosity-modifying capabilities are particularly useful in chocolate production, where it improves flow properties without significantly altering taste or appearance.

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Main Applications

In the food industry, polyricinoleate (E476) is primarily used in chocolate and confectionery products to reduce viscosity and improve processing characteristics. It allows for reduced cocoa butter content while maintaining desirable flow properties. Beyond food, this polymer finds use in cosmetic formulations as an emollient and texture enhancer. Industrial applications include its use as a lubricant additive and in certain plastic formulations where its surfactant properties are beneficial.

Safety and Storage

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Polyricinoleate is generally recognized as safe for food use within specified limits (typically 0.1-0.5% in chocolate products). Regulatory approvals vary by region, with EFSA and FDA permitting its use in certain food applications. For storage, the material should be kept in tightly sealed containers away from heat sources and direct sunlight. While not particularly hazardous, standard chemical handling precautions should be observed, including adequate ventilation in processing areas.

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B2B Procurement Guide

When sourcing polyricinoleate, buyers should specify whether food-grade material is required, as this affects both price and certification requirements. Industrial-grade material may be more economical for non-edible applications. Key procurement considerations include viscosity specifications, acid value, and hydroxyl value, which affect performance in different applications. Bulk purchases typically offer significant cost savings, with prices commonly ranging from $5 to $15 per kilogram depending on quantity and quality specifications.

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