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Polyhydroxybutyrate

Updated: 2026-08-16

Overview

Polyhydroxybutyrate (PHB) is a naturally occurring biodegradable polyester synthesized by various microorganisms as an energy storage material. It belongs to the polyhydroxyalkanoate (PHA) family and is known for its thermoplastic properties and environmental compatibility. PHB is produced through bacterial fermentation of sugars or lipids, making it a sustainable alternative to petroleum-based plastics. Its molecular structure consists of repeating 3-hydroxybutyrate units, which contribute to its crystalline nature and mechanical strength.

Physical and Chemical Properties

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PHB exhibits a high degree of crystallinity (60-80%), which affects its mechanical properties such as tensile strength and brittleness. Its glass transition temperature (Tg) ranges between 0-10°C, while its melting point is around 170-180°C. The polymer is resistant to ultraviolet light and hydrolytic degradation but is susceptible to microbial degradation in soil and marine environments. Its solubility in organic solvents like chloroform makes it suitable for processing into films, fibers, and molded products.

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Main Applications

PHB is widely used in biodegradable packaging, including food containers, agricultural films, and disposable cutlery, where environmental sustainability is prioritized. Its biocompatibility allows for medical applications such as surgical sutures, bone plates, and controlled drug delivery systems. In the textile industry, PHB fibers are explored for eco-friendly fabrics. Recent research focuses on blending PHB with other polymers to improve flexibility and reduce production costs for broader industrial adoption.

Safety and Storage

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PHB is non-toxic and approved for food-contact applications in many jurisdictions. However, dust inhalation during handling should be minimized using proper ventilation or PPE. Processed PHB products are stable under normal conditions but degrade in composting facilities within weeks. Storage recommendations include keeping the material in airtight containers at room temperature (15-25°C) with relative humidity below 50%. Prolonged exposure to moisture may initiate premature biodegradation.

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B2B Procurement Guide

When sourcing PHB, confirm the producer's fermentation technology and yield efficiency, as these impact price and quality. Certifications like EN 13432 (compostability) or USP Class VI (medical grade) should be verified based on intended use. Bulk purchasers should negotiate pricing tiers for quantities above 1 ton, with prices typically decreasing by 10-20% for large orders. Consider suppliers offering technical support for processing parameters, as PHB requires specific temperature controls during molding or extrusion.

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