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Polybutene

Updated: 2026-08-03

Overview

Polybutene (PB) is a synthetic polymer derived from butene monomers, primarily used in industrial and construction applications. It exists in various forms, including viscous liquids and semi-crystalline solids, depending on molecular weight. PB is valued for its balance of flexibility, durability, and resistance to chemicals and creep. First commercialized in the 1970s, PB gained prominence as a piping material due to its weldability and long-term stability. While its use in potable water systems has declined in some regions, it remains widely adopted in underfloor heating, industrial tubing, and specialty adhesives.

Physical and Chemical Properties

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Polybutene exhibits low density (0.91–0.92 g/cm³) and a melting range of 80–120°C, making it suitable for applications requiring thermal resistance without brittleness. Its molecular structure provides excellent stress-crack resistance and flexibility even at subzero temperatures. Chemically, PB is inert to most acids, alkalis, and solvents, though it swells in aromatic hydrocarbons. It has low oxygen permeability, a key advantage for piping systems. The polymer’s viscosity and mechanical properties can be tailored by adjusting its molecular weight distribution during synthesis.

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Main Applications

The largest application of PB is in pressure piping systems, particularly for underfloor heating and industrial fluid transport. Its thermal stability (up to 95°C continuously) and flexibility simplify installation compared to rigid materials like copper. PB also serves as a modifier in adhesives and sealants, enhancing tack and elasticity. In lubricants, it acts as a thickener, while in coatings, it improves moisture resistance. Specialty grades are used in medical tubing and food packaging films due to compliance with FDA regulations.

Safety and Storage

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Polybutene is generally non-toxic but may cause mild skin or eye irritation upon prolonged contact. Processing at high temperatures can release volatile compounds, requiring adequate ventilation. Spills should be contained with inert absorbents. Storage recommendations include keeping PB in original containers away from heat sources and oxidizers. Solid grades should be protected from UV exposure to prevent degradation. Shelf life typically exceeds two years when stored below 30°C.

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B2B Procurement Guide

When sourcing PB, specify the required melt flow index (MFI) and molecular weight, as these directly affect performance. For piping applications, verify compliance with standards like ISO 15876 or ASTM D3309. Bulk buyers should negotiate pricing tiers for orders exceeding 1 metric ton. Reputable suppliers often provide technical datasheets and batch-specific certifications. Consider regional logistics, as PB is commonly shipped in pellets (solid) or drums (liquid).

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