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Polyamide 4T

Updated: 2026-08-02

Overview

PA4T, or Polyamide 4T, is a semi-aromatic polyamide belonging to the polyphthalamide (PPA) family. It is engineered for high-performance applications due to its exceptional thermal stability and mechanical properties. Unlike standard nylons (e.g., PA6 or PA66), PA4T retains strength and rigidity at elevated temperatures, making it suitable for demanding environments. First commercialized in the late 20th century, PA4T is synthesized through polycondensation of terephthalic acid and aliphatic diamines. Its molecular structure incorporates aromatic rings, which contribute to its heat resistance and chemical inertness. The material is commonly supplied as pellets for injection molding or extrusion.

Physical and Chemical Properties

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PA4T exhibits a high melting point (290–320°C), significantly outperforming conventional nylons. Its glass transition temperature (Tg) ranges from 120–150°C, ensuring stability in continuous-use applications. The material’s tensile strength (80–100 MPa) and flexural modulus (3,000–4,000 MPa) make it ideal for structural components. Chemically, PA4T resists hydrolysis, oils, and fuels, though prolonged exposure to strong acids or bases may degrade it. Its low moisture absorption (<1% at 23°C/50% RH) minimizes dimensional changes in humid conditions, a critical advantage for precision parts.

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Main Applications

PA4T is widely adopted in the automotive industry for under-the-hood components such as sensor housings, fuel system parts, and turbocharger ducts. Its ability to withstand peak temperatures near 200°C aligns with engine compartment requirements. In electronics, PA4T serves in LED housings, connectors, and circuit board mounts due to its dielectric properties and flame retardancy (UL94 V-0 rated). Industrial uses include gears, bearings, and pump components, where wear resistance and longevity are paramount.

Safety and Storage

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PA4T pellets are generally stable at room temperature but require protection from moisture to prevent hydrolytic degradation before processing. During high-temperature molding, adequate ventilation is necessary to disperse potential fumes. Personal protective equipment (PPE) such as heat-resistant gloves and safety goggles should be worn when handling molten PA4T. Storage recommendations include sealed containers in low-humidity environments (<50% RH) and temperatures below 40°C.

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B2B Procurement Guide

When sourcing PA4T, confirm compliance with industry standards such as ISO 9001 or IATF 16949 for automotive applications. Key specifications to verify include heat deflection temperature (HDT), impact strength, and filler content (e.g., glass-reinforced grades). Bulk procurement (e.g., >1 ton) may reduce costs by approximately 10–15%. Lead times vary by supplier but typically range from 4–8 weeks. Consider regional logistics for just-in-time delivery to minimize storage costs.

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