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Platinum oxide

Updated: 2026-07-21

Overview

Platinum oxide (PtO) is an inorganic compound of platinum and oxygen, primarily existing as platinum(II) oxide. As a precious metal compound, it holds significant value in industrial applications due to its catalytic properties and chemical stability. Unlike platinum metal, platinum oxide is rarely found in nature and is typically synthesized for specific uses. Its production involves controlled oxidation of platinum under specific conditions, yielding a fine powder with consistent reactivity.

Physical and Chemical Properties

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Platinum oxide appears as a black or dark brown powder with a density of 14.1 g/cm³, reflecting its heavy metal composition. It decomposes rather than melts when heated, typically breaking down around 550°C. Chemically, PtO is insoluble in water but dissolves in strong acids, making it useful for acid-catalyzed reactions. Its semiconductor properties and surface reactivity make it valuable in electronic applications. The compound exhibits moderate stability but should be protected from strong reducing agents that could revert it to metallic platinum.

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Main Applications

The primary use of platinum oxide is as a catalyst in hydrogenation reactions, particularly in pharmaceutical and fine chemical production. Its high surface area and reactivity make it effective for selective hydrogenation processes. In energy applications, PtO serves as a component in fuel cell electrodes and other electrochemical systems. The electronics industry utilizes it for thin film deposition and as a precursor for platinum-containing materials in semiconductor devices.

Safety and Storage

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While platinum oxide isn't highly toxic, proper handling precautions are essential due to its fine particulate nature. Use NIOSH-approved respirators when handling powder to prevent respiratory irritation. Storage requires airtight containers with desiccants to prevent moisture absorption. The material should be kept separate from strong reducing agents and organic compounds. Spills should be contained and cleaned by professionals due to the compound's value and potential reactivity.

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B2B Procurement Guide

When sourcing platinum oxide, prioritize suppliers with certifications for precious metal handling. Key specifications to verify include purity (typically 99.9% or higher), particle size distribution, and surface area for catalytic applications. Consider ordering in larger quantities to benefit from bulk pricing, but ensure proper storage capabilities. Many suppliers offer customized formulations for specific industrial applications, so clearly communicate your technical requirements. Always request current assay certificates and material safety data sheets with shipments.

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