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Organically Modified Bentonite

Updated: 2026-08-20

Overview

Organic bentonite for coal is a specialty clay mineral modified with quaternary ammonium salts to enhance compatibility with hydrocarbon systems. Developed specifically for coal-related industries, it serves as a rheology modifier and suspension agent. Unlike conventional bentonite, this organically treated variant exhibits hydrophobic properties, making it ideal for stabilizing coal-water mixtures and other non-aqueous systems. Its platelet structure expands in organic media, creating three-dimensional networks that prevent particle settling.

Physical and Chemical Properties

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The material's effectiveness stems from its layered aluminosilicate structure with exchanged organic cations. These modifications increase the interlayer spacing from 12Å in natural bentonite to 18-22Å, enabling better penetration of organic molecules. Key performance indicators include gel strength (measured in lb/100ft²), yield point, and thixotropic index. Typical products achieve 90-110% swelling capacity in diesel oil within 24 hours. The organic content usually ranges 30-45% by weight, determining its activation threshold temperature (commonly 50-60°C).

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Main Applications

In coal-water slurry (CWS) production, it improves slurry stability during transport and storage, maintaining viscosity between 800-1,200 cP. The additive allows higher coal concentrations (65-70%) while reducing sedimentation. Foundry applications utilize its binding properties in coal dust-based mold coatings, enhancing metal casting surface finish. Drilling fluid formulations incorporate 2-5% organic bentonite to control fluid loss in coalbed methane extraction. Emerging uses include coal tar pitch modification and carbon electrode production.

Safety and Storage

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Though non-flammable, the powder forms explosive dust clouds at concentrations >50g/m³. Storage silos should incorporate grounding systems to prevent static discharge. Moisture exposure (>5%) causes clumping and reduced efficacy. Personal protective equipment (PPE) requirements include NIOSH-approved N95 respirators, chemical goggles, and impermeable gloves. Spills should be contained with inert absorbents like vermiculite, never washed into waterways due to potential aquatic toxicity from quaternary ammonium compounds.

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B2B Procurement Guide

Technical specifications should include: montmorillonite content (>85%), moisture (<3%), sieve residue (200 mesh pass rate >95%), and free amine content (<0.5%). Bulk shipments typically use 25kg multi-layer paper bags with PE lining. Quality verification involves laboratory tests per ISO 13500 standards for drilling applications or GB/T 20973-2007 for coal industry use. Lead times vary seasonally; winter stockpiling is recommended in cold climates where transportation may be disrupted.

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