Overview
Methyl acrylate is an ester of acrylic acid and methanol, primarily manufactured via esterification of acrylic acid or oxidation of propylene. As a BASF product, it meets stringent industrial purity standards. Its reactive vinyl group makes it a versatile monomer for copolymerization with other acrylates and vinyl compounds. The chemical is widely traded in bulk quantities (drums, isotanks, or tank trucks) for industrial use. Global production exceeds 500,000 tons annually, with major applications in Asia-Pacific and European markets. Regulatory compliance (REACH, TSCA) is mandatory for international trade.
Physical and Chemical Properties
Methyl acrylate is a low-viscosity liquid with a characteristic acrid odor. Its volatility (vapor pressure: 65 mmHg at 20°C) necessitates sealed storage. The compound readily undergoes addition reactions due to its electron-deficient double bond, enabling radical polymerization with initiators like peroxides. Key chemical behaviors include hydrolysis to acrylic acid in aqueous alkaline conditions and exothermic homopolymerization at elevated temperatures. Inhibitors (e.g., 10-100 ppm hydroquinone monomethyl ether) are typically added to prevent premature polymerization during storage and transport.
Main Applications
Over 70% of methyl acrylate is consumed in acrylic polymer production. It copolymerizes with methyl methacrylate (MMA) to modify the hardness and flexibility of plexiglass sheets. In adhesives, it enhances pressure-sensitive properties for tapes and labels. Secondary uses include textile sizing agents that improve fiber durability and water-based coatings for leather and paper. Emerging applications involve UV-curable inks and 3D printing resins, where its fast curing kinetics are advantageous. Downstream products must comply with FDA 21 CFR or EU 10/2011 regulations for food-contact materials.
Safety and Storage
Classified as a Category 2 flammable liquid (NFPA 704: H2, F3, R2), methyl acrylate requires grounding during transfer to prevent static ignition. Storage tanks should have nitrogen blanketing and temperature controls below 25°C. Spills must be contained with non-combustible absorbents like vermiculite. Personnel handling the chemical need chemical goggles, neoprene gloves, and APR masks with organic vapor cartridges. First aid measures include flushing eyes/skin with water for 15 minutes and immediate medical attention for inhalation exposure. SDS documentation must accompany all shipments.
B2B Procurement Guide
Industrial buyers should specify technical grade (≥99.5% purity) or inhibited grade (with MEHQ) depending on end-use. Bulk shipments (20+ metric tons) typically offer 10-15% cost savings versus drum quantities. Key evaluation criteria include: residual methanol content (<0.1%), water content (<0.05%), and peroxide levels. Reliable suppliers provide batch analysis certificates and comply with GHS labeling. Just-in-time procurement is discouraged due to the chemical's shelf life (6-12 months in optimal conditions). Contracts often include price adjustment clauses linked to acrylic acid feedstock costs.
Related Manufacturers
- 主营：丙烯酸甲酯、乙二醇、防冻液载冷剂
- 主营：丙二醇、丙烯酸、异丙醇、甲基丙烯酸甲酯、丙烯酸甲酯、无水乙醇、棕榈油、三乙胺、环己烷、苯酚、甲醇、丙烯酸羟乙酯、三乙醇胺、二甲基亚砜、苯扎溴铵、醋酸乙烯、丙烯酸丁酯、乙腈、二甲苯、二甲基硅油、丙烯酸异辛酯、丙烯酸羟丙酯、二甲基海因、二甲基甲酰胺DMF
- 主营：乙二醇、戊二醛、环己酮、异丙醇、二甲苯、安息油、清洗剂、正丁醇、醋酸丁酯、二氯丙烷、三氯乙烯、醋酸甲酯、无水乙醇、二氯甲烷、二氯乙烷、环保溶剂、金属洗涤剂、醋酸仲丁酯、涂料稀释剂、碳酸二甲酯、油墨稀释剂、环保化工溶剂、无色透明液体
- 主营：三氯乙烯、乙二醛、异丙醇、丙烯酸甲酯、苯乙烯、异辛醇、二氯甲烷、醋酸乙烯、二乙基乙醇胺、叔十二烷基硫醇、正十二烷基硫醇、己二胺、过硫酸铵、乙硫醇、小苏打、顺酐、苯酚、吗啉、异丙醚、过硫酸钠、三羟甲基丙烷、环氧氯丙烷、甲基丙烯酸、四氢呋喃、正辛硫醇、偶氮二异丁腈
- 主营：造纸消泡剂
- 主营：线缆挤、眼镜架、玻纤填、片管材、骨架件、保护膜、耐消毒、导光板、聚合物、日用品、内润滑、开关件、玻璃珠、聚碳酸、易流动、反射板、传感器、阻燃5va、化妆品、型棒材、透明罩、透明料、食品件、玻璃球、摩配件
- 主营：清洗剂、工业红糖、碳酸氢钠、一水柠檬酸、硫代硫酸钠、酸度调节剂、食品防腐剂、无水柠檬酸、缓冲改良剂、工业级氯化铵、食品级碳酸钠
- 主营：五金工件、涂料油墨、化工原料、医药中间体、航空煤油、二价酸酯、乙二醇、丙烯酸丁酯、二氯甲烷、环己酮、食用酒精
- 主营：淬火剂、弹性体、丁二烯、甲基丙烯酸甲酯加工、二甲苯、异丁烯、外皮套、黏结剂、实验室、丁腈胶乳、丁苯胶乳、丁苯橡胶、压力钢瓶、印染助剂、有机溶剂、合成橡胶、改性材料、合成树脂、丁基橡胶、异戊橡胶、顺丁橡胶、丙烯腈桶、异戊二烯、工程塑料、乙酰丙酸、铝合金瓶
- 主营：液碱、氢氧化钠、氨水、甲基丙烯酸甲酯、氨基磺酸、亚硫酸氢钠、漂白粉、次氯酸钙、次氯酸钠、乙醇、氢氧化钾、亚氯酸钠、二氯甲烷、硅酸乙酯、偏硅酸钠、磷酸、异丙醇、四氯乙烯、三氯乙烯、亚硝酸钠
- 主营：碳酸丙烯酯、乙二醇二醋酸酯、油漆油墨稀释剂
- 主营：苯乙烯、甲基丙烯酸缩水甘油酯GMA、醋酸乙烯、甲基丙烯酸甲酯、丙烯酸甲酯、丙烯酸丁酯、丙烯酸羟乙酯、丙烯酸异辛酯、甲基丙烯酸、丙烯酸乙酯、甲基丙烯酸酐、甲基丙烯酸羟乙酯
- 主营：丙二醇、醋酸丁酯、二丙酮醇、丙烯酸甲酯MA、单乙醇胺、四氢糠醇、二价酸酯、甲基丙烯酸羟乙酯、腰果酚、异氟尔酮、丙烯酸、二乙二醇丁醚、乙醇、妥尔油、三乙二醇、磷酸、碳酸丙烯脂、二丙二醇甲醚、二甲基亚砜、邻苯二甲酯二甲酸、轻质石油醚、溶剂油、二甲基甲酰胺、N甲基二乙醇胺
- 主营：航空煤油、石油醚、溶剂油、乙醇、甲醇、一乙醇胺、三乙醇胺、二氯甲烷、环己酮、四氢呋喃、异丙醇、丙二醇甲醚、丙二醇乙醚、丙二醇丁醚、环己烷、冰醋酸、甲基吡咯烷酮、二甲基乙醇胺、二价酸酯、四氯乙烯、乙酸乙酯、二乙二醇丁醚、己二酸二辛酯、二甲基甲酰胺、甲基叔丁基醚
- 主营：二甲基甲酰胺、DMF、异丙醇、二甲苯、丙烯酸甲酯、甲基丙烯酸甲酯、乙腈、醋酸乙烯、乙酸乙酯、四氢呋喃、二氯甲烷、无水乙醇、苯乙烯、丙烯酸、甲基吡咯烷酮、正庚烷、正己烷、环己烷
- 主营：邻苯二甲酸二辛酯、环氧大豆油、乙二醇、二乙二醇、丙二醇、丙三醇、三乙醇胺、二甲基亚砜、甲基吡咯烷酮、聚乙二醇、无水柠檬酸、桐油、氯化石蜡、乙醇、酒精、乙酸乙酯、溶剂油、冰醋酸、防冻液、甲醇、dop
- 主营：增塑洗涤剂、间二甲苯、乳化剂、丙烯酸甲酯、防冻液、丙二醇、三甲苯、苯乙烯、溶剂油、钛酸四丁酯、甲醇、乙醇、仲辛醇、异丙醇、85磷酸、碳酸丙烯酯、甲基丙烯酸、丙烯酸羟乙酯、二甲苯、脂肪酸甲酯、甲酸、氨水、丙烯酸、草酸、聚乙二醇
- 主营：苯乙烯、二甲苯、正丙醇、丙烯酸甲酯、催化剂、二乙胺、氯丙烯、巴豆醛、石油醚、防冻剂、壬基酚、乙二醇、戊二醛、异辛醇、清洗剂、丙烯酸、漂白剂、甲缩醛、氯化锌、冰醋酸、异丙醇、溶剂油、异丁醇、工业酒精、金属除锈、防结皮剂