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Magnesium Fluoride

Updated: 2026-08-05

Overview

Magnesium fluoride (MgF2) is an inorganic compound composed of magnesium and fluorine. It is valued for its optical properties, particularly its transparency to ultraviolet (UV) and infrared (IR) light. The compound occurs naturally as the rare mineral sellaite but is more commonly synthesized for industrial applications. MgF2 is widely used in anti-reflective coatings for lenses, windows, and optical instruments due to its low refractive index. Its chemical stability and resistance to high temperatures also make it suitable for specialized ceramics and metallurgical processes.

Physical and Chemical Properties

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Magnesium fluoride is a white crystalline solid with a tetragonal crystal structure. It is insoluble in water but can dissolve in nitric acid or sulfuric acid under specific conditions. The compound exhibits high thermal stability, with a melting point of 1263°C and a boiling point of 2260°C. Its optical properties include a refractive index of 1.38 at 500 nm, making it ideal for anti-reflective coatings. MgF2 is also chemically inert, resisting reactions with most solvents and gases, which contributes to its durability in harsh environments.

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Main Applications

The primary use of MgF2 is in optical coatings, where it reduces glare and enhances light transmission in lenses, telescopes, and camera components. It is also employed in UV optics due to its transparency to wavelengths as short as 120 nm. In metallurgy, magnesium fluoride serves as a flux to lower melting points in aluminum and magnesium production. Additionally, it is used in ceramics to improve thermal shock resistance and in electronics as a dielectric material.

Safety and Storage

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While MgF2 is generally stable, it should be handled with care to avoid inhalation or contact with skin and eyes. Dust exposure can irritate respiratory tracts, so PPE such as gloves and masks is recommended. Storage requires a dry, cool environment in tightly sealed containers to prevent moisture absorption. Incompatible materials include strong acids, which can dissolve the compound. Spills should be cleaned with non-reactive absorbents and disposed of according to local regulations.

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B2B Procurement Guide

When sourcing MgF2, specify purity levels (e.g., 99.9% for optical applications) and particle size distribution, as these affect performance in coatings. Suppliers may offer it in powder, pellets, or custom forms. Bulk pricing varies by quantity and purity; negotiate contracts for long-term supply to stabilize costs. Verify supplier certifications (e.g., ISO) and request material safety data sheets (MSDS) to ensure compliance with safety standards. Consider logistics, as moisture-sensitive packaging may require climate-controlled transport.

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