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Linalyl Benzoate

Updated: 2026-08-05

Overview

Linalyl benzoate is an ester derived from linalool and benzoic acid, primarily synthesized for its aromatic properties. It is widely used in the fragrance industry due to its ability to enhance and stabilize floral and citrus notes in perfumes. The compound is also employed in food flavorings, contributing a subtle sweetness reminiscent of tropical fruits. In addition to its olfactory applications, linalyl benzoate is used in aromatherapy for its calming effects. Its stability and low volatility make it a preferred choice for long-lasting scent formulations. The chemical is typically produced through esterification processes under controlled conditions to ensure high purity.

Physical and Chemical Properties

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Linalyl benzoate is a colorless to pale yellow liquid with a density slightly less than water. Its molecular structure includes a benzene ring and a linalool moiety, contributing to its distinct aroma and solubility profile. The compound is insoluble in water but readily dissolves in alcohols and essential oils, making it compatible with most cosmetic and food-grade solvents. With a boiling point around 300°C, linalyl benzoate exhibits moderate thermal stability, though it should be protected from prolonged exposure to high temperatures to prevent degradation. Its low vapor pressure ensures minimal evaporation, which is advantageous for applications requiring sustained fragrance release.

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Main Applications

The primary use of linalyl benzoate is in the perfumery industry, where it acts as a fixative to prolong the longevity of fragrances. It blends well with citrus, lavender, and woody notes, making it a versatile ingredient in both fine and functional perfumes. Additionally, it is used in soaps, detergents, and household cleaners for its pleasant scent. In the food industry, linalyl benzoate is approved as a flavoring agent in certain regions, imparting a fruity nuance to candies, beverages, and baked goods. Its non-toxic profile at low concentrations allows for safe consumption. The compound also finds niche applications in aromatherapy products, where it is valued for its purported relaxing properties.

Safety and Storage

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While linalyl benzoate is generally regarded as safe for use in cosmetics and food, industrial handlers should follow standard safety protocols. Direct skin contact may cause mild irritation, and inhalation of vapors should be avoided in poorly ventilated areas. Proper PPE, such as gloves and goggles, is recommended during bulk handling. Storage requires protection from light and heat to prevent oxidation or decomposition. Containers should be tightly sealed and kept in a cool, dry environment. Compatibility with common packaging materials like glass, HDPE, and stainless steel ensures long-term stability without degradation.

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B2B Procurement Guide

When sourcing linalyl benzoate, B2B buyers should prioritize suppliers with documented quality control measures, such as GC-MS analysis for purity verification. Certifications like ISO 9001 or GMP compliance are indicators of reliable manufacturing practices. Bulk purchases often qualify for discounts, but buyers should confirm batch consistency and lead times. Procurement teams should also assess logistical factors, including packaging options (drums, intermediate bulk containers) and regional regulatory compliance for transportation. For international shipments, ensure the supplier provides accurate SDS and customs documentation to avoid delays.

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