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Updated: 2026-07-31

Overview

Potassium Persulfate (KPS) is a white, crystalline inorganic compound with strong oxidizing properties. It is widely used in industrial applications due to its ability to initiate polymerization reactions and act as a disinfectant or bleaching agent. KPS is stable under normal conditions but decomposes when heated, releasing oxygen and sulfate radicals. This compound is commonly utilized in the production of polymers, including acrylics and styrene-based resins. Its oxidizing capabilities also make it suitable for water treatment, electronics manufacturing, and hair bleaching formulations. KPS is typically supplied in powder form and must be stored carefully to prevent decomposition or reaction with incompatible materials.

Physical and Chemical Properties

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Potassium Persulfate is characterized by its high solubility in water and stability at room temperature. The compound decomposes at around 100°C, releasing oxygen and forming potassium sulfate. Its strong oxidizing nature makes it reactive with organic materials and reducing agents, necessitating careful handling. The molecular weight of KPS is 270.32 g/mol, and its density is 2.477 g/cm³. The crystalline powder is odorless but can cause irritation upon contact with skin or eyes. In aqueous solutions, KPS dissociates to form sulfate radicals, which are highly reactive and useful in various chemical processes.

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Main Applications

KPS serves as a key initiator in emulsion polymerization reactions, particularly for acrylic and vinyl polymers. It is also employed in the electronics industry for PCB etching and cleaning processes. In water treatment, KPS acts as an oxidizer to break down organic contaminants and disinfect water supplies. Additional uses include hair bleaching formulations, where it helps lighten hair by oxidizing melanin. The textile industry utilizes KPS as a bleaching agent for fabrics. Its versatility and strong oxidizing properties make it valuable across multiple industrial sectors.

Safety and Storage

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Potassium Persulfate requires careful handling due to its oxidizing nature. It should be stored in a cool, dry place away from combustible materials and reducing agents. Proper ventilation is essential to prevent the accumulation of dust, which can pose inhalation hazards. Personal protective equipment (PPE), including gloves and safety goggles, should be worn when handling KPS. In case of skin contact, rinse immediately with plenty of water. Spills should be cleaned up promptly using non-combustible absorbents. Avoid mixing KPS with organic materials or strong acids to prevent hazardous reactions.

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B2B Procurement Guide

When procuring Potassium Persulfate, verify the CAS number (7727-21-1) and purity level, which typically ranges from 98% to 99.5%. Bulk purchases may offer cost advantages, but ensure proper storage facilities are available. Request Material Safety Data Sheets (MSDS) from suppliers to confirm handling and safety protocols. Reliable suppliers should provide certificates of analysis (CoA) to guarantee product quality. Consider packaging options, such as moisture-resistant bags or drums, to maintain stability during transport and storage. For specialized applications, consult suppliers about custom formulations or particle size distributions.

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