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Iron(III) Hydroxide

Updated: 2026-07-25

Overview

Iron(III) hydroxide, or ferric hydroxide, is an inorganic compound with the chemical formula Fe(OH)3. It is a common form of iron in its +3 oxidation state and is widely used in industrial applications due to its chemical stability and adsorption properties. This compound naturally occurs as the mineral bernalite but is more commonly synthesized for industrial use. It plays a significant role in water treatment processes, acting as a coagulant to remove impurities and heavy metals from wastewater.

Physical and Chemical Properties

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Iron(III) hydroxide appears as a brown to reddish-brown powder or gelatinous solid. It is insoluble in water but can dissolve in acids, forming iron(III) salts. The compound has a density of approximately 3.4 g/cm³ and decomposes upon heating before reaching a melting point. Its amphoteric nature allows it to react with both acids and bases. In acidic conditions, it forms iron(III) salts, while in alkaline conditions, it can form ferrate ions. These properties make it versatile in various chemical processes.

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Main Applications

Iron(III) hydroxide is primarily used in water treatment as a coagulant to remove phosphates, heavy metals, and other contaminants. Its high adsorption capacity makes it effective in purifying drinking water and industrial wastewater. In the pigment industry, it is used to produce yellow, red, and brown iron oxide pigments. It also serves as a precursor for other iron compounds, such as iron oxide and ferric chloride, which are used in pharmaceuticals, ceramics, and corrosion inhibitors.

Safety and Storage

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While iron(III) hydroxide is not highly toxic, it can cause irritation upon contact with skin or eyes. Inhalation of dust should be avoided, and proper personal protective equipment (PPE), such as gloves and masks, is recommended during handling. Storage should be in a cool, dry place, away from acids and moisture to prevent decomposition or unwanted reactions. Containers should be tightly sealed to avoid exposure to air and humidity.

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B2B Procurement Guide

When procuring iron(III) hydroxide, buyers should prioritize purity levels, which typically range from 90% to 99%. Moisture content is another critical factor, as excess moisture can affect the compound's performance in applications like water treatment. Bulk purchases often come with price discounts, but buyers should also consider logistics and storage costs. Reliable suppliers should provide certificates of analysis (CoA) to ensure product quality and consistency.

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