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Hydrazine

Updated: 2026-07-15

Overview

Hydrazine (N2H4) is a simple inorganic compound consisting of two nitrogen atoms and four hydrogen atoms. It is a highly reactive and versatile chemical, commonly used in industrial applications due to its strong reducing properties. Discovered in the late 19th century, hydrazine has since become a critical component in aerospace, pharmaceuticals, and water treatment. Hydrazine is typically produced via the Raschig process, which involves the reaction of ammonia with sodium hypochlorite. Its ability to release large amounts of energy upon decomposition makes it ideal for use as a rocket propellant. However, its toxicity and flammability require strict handling protocols.

Physical and Chemical Properties

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Hydrazine is a colorless, oily liquid with a pungent ammonia-like odor. It is highly soluble in water and polar solvents, forming hydrates that are stable under normal conditions. The compound has a density of 1.021 g/cm³ and boils at 114 °C, with a melting point of 2 °C. Chemically, hydrazine is a powerful reducing agent, capable of donating electrons in redox reactions. It reacts violently with oxidizing agents, releasing nitrogen gas and heat. Its corrosive nature necessitates the use of corrosion-resistant materials like stainless steel or specialized plastics for storage and handling.

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Main Applications

Hydrazine's primary use is in aerospace, where it serves as a monopropellant or bipropellant in rocket engines. Its ability to decompose exothermically into nitrogen and hydrogen gases makes it invaluable for thrust generation. Additionally, hydrazine is used in fuel cells and gas generators. In the pharmaceutical industry, hydrazine derivatives are employed in the synthesis of drugs such as antihypertensives and antituberculosis agents. It also plays a role in water treatment, where it acts as an oxygen scavenger to prevent corrosion in boilers and pipelines. Other applications include polymer production and agricultural chemicals.

Safety and Storage

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Hydrazine is classified as a carcinogen and is highly toxic upon inhalation, ingestion, or skin contact. Exposure can cause severe respiratory, neurological, and hepatic damage. Proper personal protective equipment (PPE), including gloves, goggles, and respirators, is essential when handling the chemical. Storage requires airtight containers made of compatible materials, kept in cool, well-ventilated areas away from heat sources and oxidizing agents. Spills should be neutralized with absorbent materials and reported immediately. Regulatory compliance, including OSHA and EPA guidelines, is mandatory for industrial use.

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B2B Procurement Guide

When procuring hydrazine, prioritize suppliers with certifications such as ISO 9001 and compliance with REACH or other regional regulations. Verify the chemical's purity, typically ranging from 98% to 99.9%, depending on the application. Bulk purchases may offer cost savings, but ensure proper storage and transportation logistics are in place. Request safety data sheets (SDS) and conduct supplier audits to assess their handling and quality control measures. Consider long-term contracts for stable pricing and supply continuity. For specialized applications, consult technical experts to confirm suitability and performance requirements.

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