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HS Code 2801801100

Updated: 2026-07-19

Overview

HS Code 2801801100 categorizes phosphorus in its various forms, including white, red, and black phosphorus, under the Harmonized System (HS) used for international trade. Phosphorus is a non-metallic element essential for life and widely used in industrial applications. White phosphorus is highly reactive and used in military and chemical applications, while red phosphorus is more stable and commonly found in safety matches and flame retardants. Black phosphorus, a newer form, has gained attention for its semiconductor properties in electronics.

Physical and Chemical Properties

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Phosphorus exhibits distinct properties depending on its allotrope. White phosphorus is a waxy, translucent solid that ignites spontaneously in air, necessitating storage under water or inert gas. Red phosphorus is a more stable, non-toxic powder used in consumer products. Black phosphorus, the least reactive form, has a layered structure similar to graphite and displays unique electronic properties. All forms are insoluble in water but vary in reactivity and physical characteristics. The molecular weight of phosphorus is 30.97 g/mol, and its density ranges from 1.82 g/cm³ for white phosphorus to 2.69 g/cm³ for black phosphorus. White phosphorus melts at 44.1°C, while red phosphorus sublimes at 590°C. These properties dictate their handling, storage, and industrial uses.

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Main Applications

Phosphorus is a versatile element with applications across multiple industries. In agriculture, it is a key component of fertilizers, essential for plant growth. The chemical industry uses phosphorus to produce phosphoric acid, detergents, and flame retardants. Red phosphorus is critical in the manufacture of safety matches and pyrotechnics. Black phosphorus is emerging as a promising material in semiconductors and optoelectronics due to its tunable bandgap. Additionally, phosphorus is used in metallurgy to improve metal properties and in water treatment to control scale formation. Its diverse applications make it a vital raw material in global trade, regulated under HS Code 2801801100.

Safety and Storage

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Handling phosphorus requires strict safety measures due to its hazardous nature. White phosphorus is highly toxic and flammable, posing risks of severe burns and environmental damage. It must be stored under water or inert gas to prevent spontaneous combustion. Red phosphorus, while less hazardous, can ignite when exposed to heat or friction and should be kept away from oxidizers. Black phosphorus is relatively stable but requires protection from moisture and light to maintain its properties. Proper labeling, ventilation, and personal protective equipment (PPE) are essential when working with phosphorus. Regulatory compliance, including transportation and disposal guidelines, must be followed to mitigate risks.

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B2B Procurement Guide

Procuring phosphorus under HS Code 2801801100 involves several considerations to ensure quality and compliance. Buyers should verify the supplier's certifications and adherence to international safety standards. Pricing varies based on purity, form, and market demand, with white phosphorus typically commanding higher prices due to its specialized applications. Logistics planning is critical, especially for white phosphorus, which requires specialized packaging and transportation under hazardous material regulations. Long-term contracts with reliable suppliers can stabilize supply chains and mitigate price volatility. Buyers should also stay informed about regulatory changes affecting phosphorus trade, such as environmental and safety laws.

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