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Furfural

Updated: 2026-07-15

Overview

Furfural is an organic compound derived from the dehydration of pentose sugars found in agricultural biomass such as corncobs, oat hulls, and sugarcane bagasse. It is one of the oldest renewable chemicals, first isolated in the 19th century. Furfural's unique structure, featuring an aldehyde group attached to a furan ring, makes it a versatile intermediate in organic synthesis. As a naturally derived chemical, furfural has gained attention in green chemistry applications. It is produced via acid-catalyzed hydrolysis and dehydration of hemicellulose, making it a sustainable alternative to petroleum-based chemicals. The global market for furfural is driven by its wide-ranging industrial applications and the growing demand for bio-based products.

Physical and Chemical Properties

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Furfural is a colorless to yellowish liquid with a characteristic almond-like odor. It has a density of 1.16 g/cm³ and boils at 161.7 °C, with a melting point of -36.5 °C. The compound is soluble in water and most organic solvents, including alcohol and ether. Chemically, furfural is reactive due to its aldehyde group and aromatic furan ring. It undergoes typical aldehyde reactions such as oxidation, reduction, and condensation. The compound is also prone to polymerization under acidic or alkaline conditions, which is a consideration in storage and handling.

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Main Applications

Furfural serves as a key raw material in the production of furan resins, which are used as binders in foundry sands and abrasives. These resins offer excellent thermal stability and resistance to chemicals, making them ideal for high-performance applications. In the pharmaceutical industry, furfural is a precursor for drugs such as nitrofurantoin, an antibiotic. It is also used in the synthesis of agrochemicals, flavors, and fragrances. Additionally, furfural finds use as a selective solvent in petroleum refining and as a starting material for biofuels and bioplastics.

Safety and Storage

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Furfural is flammable and should be stored away from heat, sparks, and open flames. It is also an irritant to the skin, eyes, and respiratory system, necessitating the use of personal protective equipment (PPE) such as gloves and goggles during handling. Proper storage conditions include a cool, dry, well-ventilated area in tightly sealed containers to prevent polymerization or degradation. In case of spills, absorb with inert material and dispose of according to local regulations. Always refer to the Material Safety Data Sheet (MSDS) for detailed safety guidelines.

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B2B Procurement Guide

When procuring furfural, B2B buyers should prioritize purity levels, typically ranging from 98% to 99.5%, depending on the application. Packaging options include drums, totes, or bulk shipments, with prices varying accordingly. It is advisable to source from suppliers with certifications such as ISO 9001 or REACH compliance to ensure quality and regulatory adherence. Buyers should also consider logistical factors, such as transportation costs and lead times, especially for international shipments. Requesting samples and conducting lab tests can help verify product quality before large-scale purchases.

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