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Ferrous Sulfite

Updated: 2026-07-20

Overview

Ferrous sulfite is an inorganic chemical compound primarily used in industrial applications. It is a reducing agent and plays a role in water treatment processes, particularly in removing heavy metals and controlling oxidation reactions. The compound is typically produced through the reaction of ferrous salts with sulfites. Due to its instability in air, ferrous sulfite is often handled under controlled conditions. It is commonly supplied as a pale green or yellowish powder, though its exact appearance can vary depending on purity and hydration levels. Industrial-grade ferrous sulfite is widely available, but high-purity forms may require specialized suppliers.

Physical and Chemical Properties

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Ferrous sulfite exhibits reducing properties, making it useful in chemical reactions where oxygen removal is required. It is slightly soluble in water, and its solutions are prone to oxidation, especially when exposed to air. The compound decomposes upon heating, releasing sulfur dioxide. In its solid form, ferrous sulfite is typically a powder with a pale green or yellowish hue. It reacts with acids to produce ferrous salts and sulfur dioxide gas. The compound's instability in air necessitates careful storage, often under inert atmospheres or in sealed containers to prevent degradation.

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Main Applications

Ferrous sulfite is primarily employed in water treatment systems, where it acts as a reducing agent to remove chlorine and other oxidizing agents. It is also used in the precipitation of heavy metals from wastewater, making it valuable in environmental remediation. In chemical synthesis, ferrous sulfite serves as a precursor for other iron compounds and as a reducing agent in organic reactions. Its ability to scavenge oxygen makes it useful in certain industrial processes where oxidation must be minimized. Additionally, it finds niche applications in photography and dye manufacturing.

Safety and Storage

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Ferrous sulfite requires careful handling due to its reactivity and potential health hazards. Workers should use personal protective equipment (PPE), including gloves and goggles, to avoid skin and eye contact. Inhalation of dust should be prevented through proper ventilation or respirators. Storage conditions are critical for maintaining the compound's stability. It should be kept in a cool, dry place, away from oxidizing agents and acids. Containers must be tightly sealed to prevent moisture absorption and oxidation. Bulk storage may require inert atmospheres or specialized packaging to prolong shelf life.

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B2B Procurement Guide

When procuring ferrous sulfite, buyers should prioritize suppliers with a proven track record in chemical distribution. Key considerations include purity levels, packaging options, and compliance with industry standards. Technical specifications should be clearly outlined in purchase agreements. Price varies depending on quantity, purity, and supplier location. Request samples for quality testing before large-scale purchases. Ensure suppliers provide proper safety data sheets (SDS) and transportation documentation. For specialized applications, consider manufacturers offering custom formulations or technical support.

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