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Ferrous Sulfate[2]

Updated: 2026-09-16

Overview

Ferrous sulfate, or iron(II) sulfate, is a widely used chemical compound with the formula FeSO4. It is commonly found in hydrated forms, such as the heptahydrate (FeSO4·7H2O), which appears as blue-green crystals. Ferrous sulfate is known for its role as a reducing agent and its ability to provide iron in various industrial and agricultural applications. Historically, ferrous sulfate was known as green vitriol and was used in dyeing and ink production. Today, it is primarily utilized in water treatment to remove phosphates, in agriculture as a soil amendment, and in the pharmaceutical industry as an iron supplement.

Physical and Chemical Properties

Ferrous sulfate exhibits several key physical and chemical properties that make it suitable for diverse applications. It is highly soluble in water but insoluble in alcohol, and it tends to oxidize in air, turning brown as it forms iron(III) sulfate. The compound is hygroscopic, meaning it absorbs moisture from the air, which can affect its stability and handling. Ferrous sulfate melts at approximately 70°C, but it decomposes at higher temperatures, releasing sulfur oxides. Its density is around 2.84 g/cm³, and it acts as a reducing agent in chemical reactions. These properties are critical for its use in water treatment and industrial processes.

Main Applications

Ferrous sulfate is employed in a variety of industries due to its versatile properties. In water treatment, it is used to precipitate phosphates and reduce chromate levels, helping to control algae growth and improve water quality. In agriculture, it serves as a soil amendment to correct iron deficiencies and lower soil pH. The pharmaceutical industry uses ferrous sulfate as an iron supplement to treat anemia. Additionally, it is a key ingredient in the production of iron pigments, such as Prussian blue, and in the manufacture of inks and dyes. Its reducing properties also make it useful in chemical synthesis and wastewater treatment.

Safety and Storage

Ferrous sulfate requires careful handling due to its irritant properties. Direct contact with skin or eyes can cause irritation, and inhalation of dust should be avoided. Personal protective equipment, such as gloves and goggles, is recommended when handling the compound. Storage conditions are critical to maintaining the stability of ferrous sulfate. It should be kept in a cool, dry place, away from oxidizing agents and moisture. Properly sealed containers are essential to prevent oxidation and degradation. In case of spills, the area should be cleaned promptly to avoid environmental contamination.

B2B Procurement Guide

When procuring ferrous sulfate for industrial or commercial use, several factors should be considered. Purity is a critical parameter, as impurities can affect performance in specific applications. Moisture content should also be verified, as hygroscopic properties can lead to clumping or degradation. Bulk purchases often come with cost advantages, but storage capacity and shelf life must be evaluated. Suppliers should provide certificates of analysis to ensure quality standards are met. Additionally, transportation and handling requirements should be discussed to prevent damage or contamination during delivery.

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