Overview
Diuron is a substituted urea herbicide first registered in 1954. As a photosynthesis inhibitor, it blocks electron transport in Photosystem II, making it effective against broadleaf weeds and grasses. The compound shows moderate persistence in soil, with degradation primarily through microbial action. In industrial contexts, diuron serves dual purposes: as an agricultural herbicide for crops like cotton and sugarcane, and as an antifouling agent in marine paints and cooling water systems. Its global market is valued at approximately $200 million annually, with major producers in China, India, and Europe.
Physical and Chemical Properties
Diuron crystallizes as odorless white needles with a density of 1.48 g/cm³. The compound demonstrates thermal stability up to 150°C but decomposes at higher temperatures, releasing toxic gases including nitrogen oxides and hydrogen chloride. Its low water solubility (42 mg/L) contributes to soil persistence, while moderate vapor pressure (1.1×10⁻⁶ Pa at 25°C) limits volatility. Diuron shows strong adsorption to organic matter in soil (Koc 480-815 mL/g), reducing leaching potential but requiring incorporation for optimal herbicidal activity.
Main Applications
In agriculture, diuron is applied pre-emergence at 1-4 kg/ha for weed control in cotton, citrus, and vineyard systems. Formulations include wettable powders (WP), water-dispersible granules (WG), and flowable concentrates (SC). Industrial uses include: antifouling in marine paints (0.5-2% concentration), algicide in cooling towers (0.1-0.5 ppm), and vegetation control on railways and utility rights-of-way. Recent innovations include microencapsulated formulations for reduced environmental impact and combination products with diquat for aquatic weed management.
Safety and Storage
Diuron is classified as Acute Toxicity Category 4 (harmful if swallowed) and causes serious eye irritation. Chronic exposure risks include potential carcinogenicity (EPA: Likely Human Carcinogen) and endocrine disruption. Storage requires sealed containers in ventilated areas below 30°C, separated from foodstuffs. Spill management involves containment with inert absorbents (vermiculite or sand), avoiding water flushing. Personal protective equipment (PPE) should include nitrile gloves, goggles, and respiratory protection during handling. Shelf life typically exceeds 2 years when stored properly.
B2B Procurement Guide
Technical grade diuron (≥98% purity) dominates bulk purchases. Key specifications include: moisture content (<0.5%), insoluble matter (<0.1%), and particle size distribution (D90 <45μm for WP formulations). Procurement should verify: REACH registration status (EU), EPA establishment number (US), and local regulatory approvals. MOQs from Chinese manufacturers typically start at 1 metric ton, with 25kg woven bags being the standard packaging. Third-party lab analysis is recommended for impurity profiling, particularly for 3,4-dichloroaniline (DCA) content which affects product stability.
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