Dihydrocoumarin
Overview
Dihydrocoumarin is an organic compound derived from coumarin, featuring a saturated lactone ring. It is widely recognized for its sweet, herbaceous aroma, resembling freshly cut hay or vanilla. Industrially, it serves as a precursor or additive in fragrances, food flavorings, and pharmaceutical syntheses. First synthesized in the late 19th century, dihydrocoumarin is now produced via hydrogenation of coumarin or through chemical synthesis from phenol derivatives. Its stability and pleasant odor make it a staple in perfumery and cosmetic formulations.
Physical and Chemical Properties
Dihydrocoumarin exists as a colorless to pale yellow liquid or solid, depending on temperature, with a melting point of 24-26°C and a boiling point of 272°C. Its density is 1.186 g/cm³, and it is soluble in organic solvents like ethanol but only marginally in water. The compound is chemically stable under standard conditions but may degrade when exposed to strong acids, bases, or oxidizers. Its lactone structure contributes to its characteristic odor and reactivity in esterification reactions.
Main Applications
In the fragrance industry, dihydrocoumarin is used to impart sweet, woody notes to perfumes, soaps, and detergents. It is also a key flavoring agent in foods, beverages, and tobacco products, often labeled as 'tonka bean' or 'vanilla' substitute. Pharmaceutical applications include its use as an intermediate in anticoagulant drugs and antimicrobial agents. Additionally, it finds niche roles in agrochemicals and as a UV absorber in plastics.
Safety and Storage
Dihydrocoumarin is generally low in toxicity but may irritate skin, eyes, or respiratory tracts upon direct contact. Proper handling requires gloves, goggles, and ventilation. Storage should be in tightly sealed containers, away from heat and incompatible substances like oxidizers. Regulatory compliance varies by region; for example, the FDA approves it as a flavoring agent in limited quantities, while the EU regulates its use under REACH.
B2B Procurement Guide
When sourcing dihydrocoumarin, prioritize suppliers with ISO or GMP certifications to ensure quality. Key specifications include purity (≥98%), CAS verification, and batch testing reports. Bulk pricing typically decreases for orders above 100 kg. Logistics should account for its liquid/solid transition near room temperature; shipping may require temperature-controlled containers. Always request Material Safety Data Sheets (MSDS) and compliance documentation for your industry.
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