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Copper(I) chloride

Updated: 2026-08-02

Overview

Copper(I) chloride, also known as cuprous chloride, is an inorganic compound with the chemical formula CuCl. It is a white or grayish-white powder that is insoluble in water but soluble in ammonia and hydrochloric acid. This compound is primarily used in organic synthesis and as a catalyst in various chemical reactions. Copper(I) chloride is valued for its reducing properties and its role in facilitating reactions such as the Sandmeyer reaction. It is also a precursor in the production of pigments and is used in electroplating processes. Due to its reactivity, it must be handled with care to avoid exposure to moisture and oxidizing agents.

Physical and Chemical Properties

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Copper(I) chloride has a molecular weight of 98.999 g/mol and a density of 4.14 g/cm³. It melts at 423°C and boils at 1,490°C, making it stable under high temperatures. The compound is insoluble in water but dissolves in ammonia and hydrochloric acid, forming complex ions. One of the key chemical properties of CuCl is its ability to act as a reducing agent. It is also used as a catalyst in organic reactions, such as the synthesis of aryl chlorides. Its low solubility in water makes it suitable for applications where water resistance is required, such as in pigments and coatings.

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Main Applications

Copper(I) chloride is widely used in organic synthesis, particularly in the Sandmeyer reaction for producing aryl chlorides. It is also employed as a catalyst in the production of silicone rubbers and other polymers. In the pigment industry, CuCl is a precursor for producing blue and green pigments. Additionally, copper(I) chloride is used in electroplating to deposit copper onto surfaces. Its reducing properties make it useful in photographic development and as a decolorizing agent in the petroleum industry. The compound's versatility ensures its demand across multiple industrial sectors.

Safety and Storage

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Copper(I) chloride is harmful if swallowed or inhaled and can cause skin and eye irritation. Proper protective equipment, such as gloves and goggles, should be worn when handling this compound. It should be stored in a cool, dry, and well-ventilated area away from moisture and oxidizing agents. In case of exposure, rinse the affected area with plenty of water and seek medical attention if necessary. Spills should be contained and cleaned up immediately to prevent environmental contamination. Always follow local regulations for the disposal of chemical waste.

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B2B Procurement Guide

When procuring copper(I) chloride, verify the purity level, as industrial applications typically require 99% or higher purity. Check supplier certifications to ensure compliance with industry standards. Packaging should be intact to prevent moisture ingress, which can degrade the product. Bulk orders may offer cost savings, but ensure the supplier can meet your volume requirements. Consider logistics and storage conditions to maintain product quality. Request samples for testing if you are working with a new supplier to confirm the product meets your specifications.

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