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Citronellal

Updated: 2026-07-15

Overview

Citronellal is a monoterpenoid aldehyde that occurs naturally in the essential oils of various plants, particularly citronella grass and lemon eucalyptus. It is a key component in the fragrance and flavor industries due to its fresh, citrus-like aroma. The compound is also used as a starting material in the synthesis of menthol and other terpenoids. In recent years, bio-citronellal has gained attention as a sustainable alternative to synthetic versions, often derived from renewable plant sources. This aligns with the growing demand for eco-friendly and natural ingredients in consumer products.

Physical and Chemical Properties

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Citronellal is a colorless to pale yellow liquid with a strong, characteristic lemon-like odor. It is less dense than water and has a boiling point around 207-209°C. The compound is volatile and flammable, requiring careful handling and storage. Chemically, citronellal is an unsaturated aldehyde, making it reactive in various chemical processes. It can undergo hydrogenation to form citronellol or cyclization to produce isopulegol, a precursor to menthol. Its solubility profile allows it to be used in both aqueous and organic formulations.

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Main Applications

The primary use of citronellal is in the fragrance industry, where it imparts a fresh, citrus note to perfumes, soaps, and detergents. It is also employed as a flavoring agent in food products, providing a lemony taste. Beyond its sensory applications, citronellal serves as an effective insect repellent, particularly against mosquitoes. This has led to its inclusion in many natural insect repellent formulations. Industrially, it is a valuable intermediate in the synthesis of menthol and other terpenoid compounds.

Safety and Storage

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Citronellal should be handled with care as it can cause skin and eye irritation. Proper personal protective equipment, including gloves and goggles, is recommended when working with this compound. It is also flammable and should be kept away from open flames and heat sources. For storage, citronellal should be kept in a cool, dry place in tightly sealed containers to prevent oxidation and evaporation. Containers should be made of materials resistant to organic solvents, such as stainless steel or certain plastics.

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B2B Procurement Guide

When procuring citronellal for business purposes, buyers should pay attention to several key factors. The purity level is crucial, as it affects the compound's performance in various applications. Natural and synthetic versions may have different price points and regulatory considerations. It's also important to verify the supplier's ability to provide consistent quality and volume. Certificates of analysis and compliance with relevant regulations (such as REACH or FDA) should be requested. For international shipments, proper documentation for hazardous materials may be required due to citronellal's flammability.

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