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Chlorooctane

Updated: 2026-07-15

Overview

Chlorooctane, also known as 1-chlorooctane or octyl chloride, is a halogenated hydrocarbon with the chemical formula C8H17Cl. It is a colorless to pale yellow liquid with a characteristic odor. Chlorooctane is primarily used as an intermediate in organic synthesis, particularly in the production of surfactants, pharmaceuticals, and agrochemicals. Due to its reactivity and solubility in organic solvents, chlorooctane is a versatile building block in the chemical industry. It is commonly employed in alkylation reactions and as a precursor for longer-chain compounds. Industrial applications often require high-purity grades to ensure optimal reaction yields.

Physical and Chemical Properties

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Chlorooctane is a volatile liquid with a density of approximately 0.87 g/cm³, making it less dense than water. It has a relatively low melting point of -70 °C and boils between 180-182 °C. The compound is insoluble in water but readily dissolves in common organic solvents such as ethanol, ether, and acetone. Chemically, chlorooctane is reactive toward strong oxidizing agents and may decompose under high temperatures to release toxic gases like hydrogen chloride. Its flammability requires careful handling, and it should be stored away from ignition sources. The presence of the chlorine atom makes it a useful electrophile in nucleophilic substitution reactions.

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Main Applications

The primary use of chlorooctane is as an intermediate in organic synthesis. It serves as a key raw material for producing surfactants, such as quaternary ammonium compounds used in fabric softeners and disinfectants. The compound is also employed in the manufacture of pharmaceuticals, where it acts as an alkylating agent. In industrial settings, chlorooctane is utilized as a solvent for resins and waxes, as well as a degreasing agent. Its role in agrochemical synthesis includes the production of herbicides and pesticides. Specialty applications include its use in research laboratories for catalytic studies and polymer chemistry.

Safety and Storage

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Chlorooctane poses several hazards, including skin and eye irritation, respiratory tract irritation, and potential central nervous system effects if inhaled. Proper personal protective equipment (PPE), such as gloves, goggles, and respirators, should be worn when handling this chemical. Storage recommendations include keeping the compound in tightly sealed containers in a cool, dry, and well-ventilated area. It should be segregated from oxidizing agents and incompatible materials. Spills should be contained using inert absorbents, and disposal must comply with local environmental regulations. Emergency procedures should include ventilation and the use of appropriate fire extinguishers for flammable liquid fires.

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B2B Procurement Guide

When procuring chlorooctane, buyers should prioritize suppliers that provide detailed technical specifications, including purity levels (typically 98% or higher for industrial use). Key documents to request include the Safety Data Sheet (SDS) and Certificate of Analysis (COA) to verify quality and compliance with regulatory standards. Bulk purchases often offer cost advantages, but storage capacity and shelf-life considerations must be evaluated. Lead times may vary depending on supplier inventory and regional availability. For international shipments, ensure proper hazardous material labeling and transportation compliance. Establishing long-term contracts with reputable manufacturers can secure consistent supply and favorable pricing.

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