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Calprene

Updated: 2026-08-03

Overview

Calprene is a styrene-butadiene copolymer (SBC) developed for industrial applications requiring flexibility, durability, and adhesion. Produced via solution polymerization, it combines polystyrene's rigidity with polybutadiene's elasticity. Its customizable styrene-butadiene ratio allows tailored properties for specific uses. As a thermoplastic elastomer, Calprene bridges the gap between rubbers and plastics. It is favored in sectors like construction and automotive for its balance of processability and performance. Manufacturers often blend it with bitumen or other polymers to enhance end-product characteristics.

Physical and Chemical Properties

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Calprene exhibits low density (0.94-0.96 g/cm³) and amorphous structure, lacking a defined melting point. Its glass transition temperature ranges from -60°C to 100°C, ensuring flexibility across climates. The polymer resists UV degradation and oxidation, critical for outdoor applications like road paving. Solubility in solvents like toluene and acetone facilitates formulation into adhesives. Its non-polar nature ensures compatibility with hydrocarbons but limits water absorption (<0.1%). Mechanical properties include high elongation (up to 1,000%) and tensile strength (5-20 MPa), varying by grade.

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Main Applications

In construction, Calprene modifies bitumen for waterproofing membranes and road surfaces, improving crack resistance. Adhesive manufacturers use it in pressure-sensitive tapes and labels due to its tackiness. Footwear soles benefit from its cushioning and abrasion resistance. The packaging industry employs Calprene in films and hot-melt adhesives for carton sealing. Automotive applications include noise-damping mats and interior trim. Its FDA-compliant grades are suitable for food-contact materials like cling films.

Safety and Storage

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Calprene is generally safe but requires standard polymer-handling precautions. Dust inhalation should be avoided; use NIOSH-approved respirators in dusty environments. Skin contact is non-irritating, but gloves are recommended during prolonged handling. Store pellets in sealed containers below 40°C to prevent clumping. Keep away from open flames—though self-extinguishing, it emits smoke when burned. Disposal should follow local regulations for synthetic polymers, prioritizing recycling where feasible.

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B2B Procurement Guide

Buyers should specify technical requirements: styrene content (e.g., 30-40%), viscosity, or block/gradient copolymer structure. Grades like Calprene 501 (high adhesion) or 512 (low odor) cater to distinct needs. Bulk orders (20+ tons) often qualify for discounts. Verify supplier certifications (ISO 9001) and request samples for compatibility testing. Lead times vary; Asian suppliers may offer lower prices but longer shipping. Contracts should include quality guarantees and batch-testing protocols.

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