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Calcium Alkoxide

Updated: 2026-08-05

Overview

Calcium methoxide is a white to off-white powder with the chemical formula Ca(OCH3)2. It is a strong base and a versatile catalyst, particularly in organic synthesis and biodiesel production. The compound is highly reactive with water and must be handled under anhydrous conditions. Calcium methoxide is synthesized by the reaction of calcium metal or calcium hydride with methanol. Due to its moisture sensitivity, it is typically stored under an inert atmosphere such as nitrogen or argon. Its catalytic properties make it valuable in industrial applications, especially where high basicity is required.

Physical and Chemical Properties

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Calcium methoxide appears as a white to off-white powder with a molecular weight of 102.15 g/mol. It decomposes before reaching its melting point and is highly soluble in methanol, but reacts violently with water. The compound is a strong base, making it useful in various chemical reactions. Its moisture sensitivity necessitates careful handling and storage under inert conditions. The density and boiling point are not well-documented due to its decomposition characteristics. The compound's reactivity with water limits its use in aqueous environments, but it excels in anhydrous organic reactions.

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Main Applications

Calcium methoxide is primarily used as a catalyst in biodiesel production, where it facilitates the transesterification of fats and oils into fatty acid methyl esters (FAME). Its strong basicity makes it effective in this role, often outperforming other catalysts like sodium methoxide. In organic synthesis, calcium methoxide is employed in reactions requiring a strong base, such as condensations and esterifications. It is also used in the production of pharmaceuticals and fine chemicals. Its ability to catalyze reactions under mild conditions makes it a preferred choice in many industrial processes.

Safety and Storage

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Calcium methoxide is corrosive and reacts violently with water, releasing methanol and heat. Proper protective equipment, including gloves and goggles, must be worn when handling this compound. Storage should be in a cool, dry place under an inert atmosphere to prevent degradation. Spills should be managed with dry absorbents, and water should never be used to clean up calcium methoxide. The compound should be kept away from moisture and acids to avoid hazardous reactions. Proper ventilation is essential to prevent the accumulation of methanol vapors, which can be toxic.

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B2B Procurement Guide

When procuring calcium methoxide, B2B buyers should prioritize suppliers with a proven track record of quality and reliability. Key factors to consider include purity levels, typically ranging from 95% to 99%, and packaging integrity to ensure moisture-free storage. Bulk purchases often come with cost advantages, but buyers should verify storage capabilities to maintain product quality. Certificates of analysis (CoA) should be requested to confirm chemical specifications. Additionally, suppliers should provide safety data sheets (SDS) to ensure compliance with handling and transportation regulations.

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