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Bromine-Potassium Bromide Solution

Updated: 2026-08-16

Overview

Potassium bromide bromine solution is a laboratory reagent composed of potassium bromide dissolved in a bromine solution. It serves as a safer alternative to handling pure bromine, which is highly volatile and hazardous. The solution is commonly used in organic chemistry for bromination reactions, where it introduces bromine atoms into organic compounds. This reagent is also employed in pharmaceutical quality control to test for unsaturation in organic molecules. Its reddish-brown color and distinct odor make it easily identifiable. Due to its reactivity, it must be prepared and stored with care to prevent degradation or accidental exposure.

Physical and Chemical Properties

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The solution appears as a reddish-brown liquid with a pungent odor due to the presence of bromine. It is denser than water and miscible with many organic solvents. The bromine component is highly reactive, making the solution a strong oxidizing agent. When exposed to air, the solution can release bromine vapor, which is toxic and corrosive. The potassium bromide acts as a stabilizer, reducing the volatility of bromine. The solution's pH is typically acidic, and it reacts vigorously with reducing agents and flammable materials.

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Main Applications

The primary use of potassium bromide bromine solution is in organic synthesis for bromination reactions, where it adds bromine atoms to alkenes and alkynes. It is also a key reagent in the bromine test, which detects unsaturation in organic compounds. In the pharmaceutical industry, it is used to verify the purity of raw materials and finished products. Additionally, the solution serves as a disinfectant in water treatment and laboratory settings due to its strong antimicrobial properties. Its versatility makes it a staple in many chemical and analytical laboratories.

Safety and Storage

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Due to its corrosive and toxic nature, potassium bromide bromine solution requires strict safety measures. Always use personal protective equipment (PPE), including gloves, goggles, and a lab coat, when handling this reagent. Work should be conducted in a fume hood to prevent inhalation of bromine vapors. Store the solution in amber glass bottles to protect it from light, which can degrade the bromine. Keep containers tightly sealed and in a cool, well-ventilated area away from incompatible materials such as reducing agents and organic compounds. Spills should be neutralized with a reducing agent like sodium thiosulfate.

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B2B Procurement Guide

When procuring potassium bromide bromine solution, buyers should confirm the concentration and purity required for their specific applications. Reputable suppliers should provide certificates of analysis (CoA) and material safety data sheets (MSDS). Bulk purchases may offer cost savings, but ensure proper storage facilities are available. Consider suppliers who adhere to international safety standards and can provide technical support. For reference, prices typically range from $20 to $50 per liter, depending on purity and quantity.

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