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Bis(2-bromoethyl) ether

Updated: 2026-07-15

Overview

Bis(2-bromoethyl) ether is an organobromine compound primarily used as a reactive intermediate in organic synthesis and polymer chemistry. Its molecular structure consists of two bromoethyl groups linked by an oxygen atom, making it a versatile alkylating agent. The compound is classified as hazardous due to its toxicity and reactivity. Industrial production follows strict protocols to minimize exposure risks. It is typically supplied in amber glass bottles or specialized containers to prevent degradation.

Physical and Chemical Properties

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As a brominated ether, bis(2-bromoethyl) ether exhibits high density (1.79 g/cm³) and moderate boiling point (210-215°C). Its molecular weight is 247.92 g/mol with the formula C4H8Br2O. The liquid is colorless to pale yellow with a characteristic ether-like odor. The compound demonstrates good solubility in most organic solvents but negligible water solubility. It is highly reactive with nucleophiles and participates readily in substitution reactions. Thermal decomposition may release toxic bromine compounds, requiring careful temperature control during handling.

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Main Applications

In industrial chemistry, bis(2-bromoethyl) ether serves as a crucial intermediate for synthesizing specialty chemicals. Its primary use involves introducing bromoethyl groups into target molecules during pharmaceutical and agrochemical production. The compound also functions as a crosslinking agent in polymer chemistry, particularly for modifying epoxy resins and other thermosetting materials. Some advanced applications include its use in liquid crystal production and as a reagent in organic transformations.

Safety and Storage

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Proper handling of bis(2-bromoethyl) ether requires comprehensive safety measures. The compound is classified as toxic (T), corrosive (C), and harmful (Xn) under GHS standards. Mandatory PPE includes chemical-resistant gloves, face shields, and respiratory protection when vapors may be present. Storage should occur in tightly sealed containers under inert atmosphere when possible. Secondary containment is recommended to prevent environmental contamination in case of leaks. Shelf life is typically 1-2 years when stored properly at temperatures below 25°C.

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B2B Procurement Guide

When procuring bis(2-bromoethyl) ether, buyers should prioritize suppliers with certified quality control systems. Key specifications to verify include purity (≥95%), water content (<0.5%), and absence of heavy metal contaminants. Bulk purchases (25kg+ drums) generally offer better pricing but require appropriate storage facilities. Many suppliers provide technical support for handling and application questions. Consider requesting small test quantities before large orders to verify product quality meets your process requirements.

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