Overview
Beta Zeolite (BEA structure) is a synthetic molecular sieve with a three-dimensional 12-membered ring pore system, first developed by Mobil in the 1960s. It is distinguished by its high silica-to-alumina ratio (SiO2/Al2O3 typically 10-300), which enhances thermal and hydrothermal stability. The material's unique acidity and pore architecture make it indispensable in refining and chemical synthesis. Unlike earlier zeolites like ZSM-5, Beta Zeolite's intergrown polymorphs create interconnected channels, improving mass transfer in catalytic reactions. Industrial grades are often modified with metals (e.g., Pt, Ni) for specific processes. Production involves hydrothermal synthesis using tetraethylammonium hydroxide as a structure-directing agent.
Physical and Chemical Properties
Beta Zeolite exhibits a BET surface area of 500-700 m²/g and pore diameters of 0.66 x 0.67 nm (straight channels) and 0.56 x 0.56 nm (sinusoidal channels). Its framework density is ~1.7 g/cm³, with strong Brønsted acidity due to aluminum substitution in the silica matrix. The material maintains structural integrity up to 900°C in air and resists acids (except HF). Notably, its hydrophobicity increases with higher SiO2/Al2O3 ratios, making it effective for organic-phase reactions. Ion-exchange capacity varies with aluminum content, allowing customization for specific catalytic needs. Characterization typically involves XRD for crystallinity, NMR for Al coordination, and nitrogen adsorption for pore analysis.
Main Applications
In petroleum refining, Beta Zeolite catalysts dominate hydrocracking of heavy oils to diesel/jet fuel (e.g., Chevron's ISOCRACKING process). Its shape-selective properties enable xylene isomerization in PX production, outperforming older catalysts. The zeolite also serves in alkylation (cumene synthesis) and dewaxing of lubricants. Emerging uses include biomass conversion (e.g., fructose to HMF) and CO2 capture due to tunable adsorption sites. In detergents, modified forms replace phosphates as water softeners. Environmental applications involve VOC abatement and NOx reduction in automotive exhaust systems when combined with transition metals like copper.
Safety and Storage
As a fine powder, Beta Zeolite poses mild inhalation risks (TLV 10 mg/m³ for nuisance dust). No significant toxicity is reported, but dust control via local exhaust ventilation is recommended. Spills should be vacuumed dry; water flushing may disperse particles. Long-term storage requires moisture-proof packaging (often vacuum-sealed with desiccants) to prevent acidity loss. Bulk containers must avoid compaction to preserve crystallinity. Compatibility testing is advised when blending with other catalysts (e.g., rare-earth Y zeolites) to prevent unintended reactions. Transport classifications typically fall under NON-Hazardous for most regulations.
B2B Procurement Guide
Industrial buyers should specify: 1) SiO2/Al2O3 ratio (e.g., 25 for cracking, 150 for isomerization), 2) Crystallinity (>90% by XRD), 3) Binder content (if extruded forms are needed), and 4) Metal loading (for pre-modified catalysts). Sample testing via NH3-TPD (acidity) and n-hexane adsorption (pore volume) is critical. Major producers include Zeolyst International, Clariant, and Tosoh Corporation. Prices scale with purity—research-grade (99.9%) costs 3-5x industrial-grade. MOQ for bulk orders is commonly 1 metric ton. Lead times vary from 2 weeks (standard grades) to 3 months (custom formulations). Consider FOB China prices at $80-$120/kg for 10-ton contracts.
Related Manufacturers
- 主营：Y型分子筛、钛硅分子筛、A型分子筛、ZSM-5分子筛、SSZ-13分子筛、β分子筛、超稳USY分子筛、VOCs吸附分子筛、沸石分子筛
- 主营：塔填料、带刺花环、加厚浮球、13X分子筛的孔径10A、塑料阶梯环、废水处理塔、塑料空心球、塑料矩鞍环、塑料环保球、泰勒花环填料、环保化工填料、塑料空心浮球、聚丙烯塑料花环、洗涤塔专用填料、吸收塔专用填料
- 主营：雪花环、鲍尔环、六棱环、13x分子筛、悬浮球、生物球、活性炭、三丫环、陶瓷轻瓷、面覆盖球、金属扁环、泡沫陶瓷、蜂窝斜管、蜂窝陶瓷、开孔瓷球、生物填料、金属拉西环、塑料环保球、开孔十字环、陶瓷蓄热体、陶瓷拉西环、陶瓷阶梯环、塑料阶梯环、多面空心球、陶瓷研磨球
- 主营：气浮机、废气治理、除臭设备、分子筛、废气净化塔、废气净化器、污水处理设备、玻璃钢喷淋塔、废气净化设备、催化燃烧设备、粉尘处理设备、废气净化装置、废水净化装置、废水处理设备、污水净化装置、废气净化处理、废气催化燃烧
- 主营：铝酸钠、偏铝酸钠、中性氧化铝、分子筛、药用层析氧化铝、活性氧化铝、丁基胶乳、丁基手套
- 主营：分子筛、催化燃烧设备
- 主营：蜂窝形沸石分子筛、轻集料混凝土、建筑回填陶粒
- 主营：选粉机设备、滤筒除尘器、拌湿机设备、RCO沸石分子筛、布袋除尘器、油烟处理设备、废气处理设备、催化燃烧设备、电捕焦油器设备、除尘器布袋、喷淋塔、蓄热式焚烧炉、卸料器、插板阀
- 主营：干燥剂脱硫、空气压缩机、制氮设备、碳分子筛、4A碳分子筛、制氮机分子筛、3a碳分子筛、5a碳分子筛、分子筛、进口碳分子筛、4A分子筛、13X分子筛、5A分子筛、氧分子筛、干燥机分子筛、PSA制氮机分子筛、氧化铝球、3KT-172、GN-UC-H、1.5GN-H、CMS-240、CMS-300、CMS-260、CMS-280、活性氧化铝
- 主营：催化燃烧设备、螺旋输送机、刮板输送机、分子筛、皮带输送机、布袋除尘器、滤筒除尘器、旋风除尘器、粉尘加湿机、星型卸料器、仓顶除尘器、活性炭吸附箱、油烟净化器、喷淋塔、气旋塔、斗式提升机、空气输送斜槽、生石灰消化器、料仓、卸灰阀、关风机、补偿器、湿电除尘器、电捕焦油器、打散机
- 主营：瓷球、陶粒滤料、铁碳填料、沸石分子筛、塑料填料、陶瓷填料、金属填料、耐酸砖、氨水过滤器
- 主营：超细硅酸铝粉、硅藻土、膨润土、分子筛、高岭土、滑石粉、彩砂、透明粉、白炭黑、金刚砂、石墨、海泡石、木粉、轻钙、重钙、玻璃粉、贝壳粉、凹凸棒土、玻璃鳞片、陶土、铝矾土、火山岩、电气石粉、合成云母、赤铁粉
- 主营：双功能催化剂、负载金属催化剂、金属脱氧剂、分子筛催化剂、分子筛、分子筛活化粉、分子筛脱水剂、ZSM-5分子筛、Y型分子筛、多级孔分子筛、介孔分子筛、分子筛吸附剂、介孔材料、钯系催化剂、聚氨酯除水剂、加氢催化剂、异构化催化剂、环化反应催化剂、甲基化催化剂、吡啶合成催化剂
- 主营：脱氧剂、催化剂、干燥剂、分子筛、zsm-5分子筛、脱硫脱氨分子筛、beta分子筛、溶剂干燥分子筛、吸附剂、钯触媒、voc吸附、活化粉、沸石吸附、贵金属催化剂、钯催化剂、酸性气体干燥、钛硅催化剂、异构化催化剂、加氢催化剂、sapo-34、ssz-13、NaY
- 主营：VOCs废气处理设备、除尘设备、净化车间相关、分子筛、喷漆房、烤漆房、rco、rto