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Anionic Hydroxy Silicone Oil

Updated: 2026-07-15

Overview

Anionic hydroxy silicone oil is a specialized organosilicon polymer featuring reactive hydroxyl groups and anionic character. As a modified silicone fluid, it combines the inherent heat resistance and flexibility of silicones with enhanced water solubility and fiber affinity. This chemical is particularly valued in textile finishing where it imparts durable softness without compromising fabric breathability. Its anionic nature improves compatibility with cotton and other cellulosic fibers compared to conventional silicone softeners.

Physical and Chemical Properties

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The material typically appears as a viscous liquid with viscosity ranging from 500 to 100,000 mPa·s at 25°C depending on molecular weight. Its hydroxyl content generally falls between 5-8%, which determines reactivity in subsequent processing. Unlike conventional silicone oils, the anionic modification provides self-emulsifying properties, allowing easier formulation into aqueous systems. The compound demonstrates exceptional thermal stability, maintaining performance up to 200°C, and shows good resistance to oxidation and yellowing.

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Main Applications

In textile manufacturing, this silicone oil serves as a premium softening agent for natural and synthetic fabrics, particularly where durable softness is required. It reduces fiber friction by 40-60% compared to untreated fabrics while maintaining moisture permeability. The personal care industry utilizes it in hair conditioners and skin care products due to its exceptional spreadability and non-greasy feel. Industrial applications include mold release agents for rubber products and foam stabilizers in polyurethane production. Recent developments explore its use in eco-friendly fabric coatings as a formaldehyde-free alternative.

Safety and Storage

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While classified as low toxicity, proper handling precautions should be observed. The material may cause temporary eye irritation and requires immediate flushing with water if contact occurs. Skin protection is recommended during bulk handling. Storage requires protection from extreme temperatures and moisture. Bulk containers should be nitrogen-purged to prevent viscosity changes. Shelf life typically exceeds 12 months when stored properly. In case of spills, absorb with inert material and dispose according to local regulations.

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B2B Procurement Guide

Industrial buyers should specify technical parameters including hydroxyl value (typically 0.5-1.2%), viscosity range, and anionic content (usually 15-30%). Pharmaceutical-grade variants command 20-30% premium over industrial grades. Quality verification should include tests for emulsion stability (4 hours at 3000 rpm centrifugation) and pH value (6.5-7.5). Leading manufacturers are concentrated in China, Germany and the United States, with minimum order quantities commonly starting at 200kg for standard grades.

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