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Ammonium Pentaborate

Updated: 2026-07-31

Overview

Ammonium pentaborate is a borate compound primarily used as an analytical reagent in laboratories. Its chemical formula, NH4B5O8·4H2O, reflects its composition of ammonium ions and borate groups with four water molecules. This compound is valued for its stability and solubility in water, making it suitable for various chemical analyses and industrial processes. In addition to its role in analytical chemistry, ammonium pentaborate serves as a flame retardant and a component in the production of specialty glasses and ceramics. Its ability to release boron at high temperatures enhances its utility in fire-resistant materials and other high-temperature applications.

Physical and Chemical Properties

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Ammonium pentaborate appears as a white crystalline powder with a density of 1.58 g/cm³. It is hygroscopic, meaning it absorbs moisture from the air, which necessitates careful storage in sealed containers. The compound decomposes at around 120°C, releasing water and ammonia, and is soluble in water but only slightly soluble in alcohol. Its stability under normal conditions and non-flammable nature make it a safe choice for many laboratory and industrial applications. However, its hygroscopicity requires handling in low-humidity environments to prevent degradation and maintain its efficacy as a reagent.

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Main Applications

Ammonium pentaborate is widely used as an analytical reagent in laboratories for titration and other chemical analyses. Its precise boron content makes it ideal for calibrating instruments and preparing standard solutions. Beyond laboratories, it acts as a flame retardant in textiles, plastics, and wood products, where it releases boron to inhibit combustion. In industrial settings, ammonium pentaborate is a key ingredient in the manufacture of borosilicate glasses and ceramics, where it improves thermal and chemical resistance. It also finds use in metallurgy as a flux and in agriculture as a micronutrient fertilizer, though these applications are less common compared to its analytical and flame-retardant uses.

Safety and Storage

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While ammonium pentaborate is generally safe, it requires proper handling to avoid health risks. Inhalation of dust or contact with skin and eyes can cause irritation, so protective gloves, goggles, and masks are recommended. In case of exposure, rinse affected areas with plenty of water and seek medical advice if symptoms persist. Storage should be in a cool, dry place, away from moisture and incompatible substances like strong acids. Sealed containers are essential to prevent absorption of moisture, which can compromise the reagent's quality. Proper labeling and segregation from food and beverages are also critical to avoid accidental ingestion.

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B2B Procurement Guide

When procuring ammonium pentaborate, B2B buyers should prioritize suppliers who provide a Certificate of Analysis (COA) to verify purity and composition. Bulk purchases often offer cost advantages, but ensure the supplier has adequate storage facilities to maintain product integrity. Consider the reagent's intended use—higher purity grades (e.g., 99%+) are essential for analytical applications, while industrial uses may tolerate lower grades. Lead times and logistics should also be evaluated, especially for international shipments, to ensure timely delivery and compliance with local regulations regarding chemical imports.

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