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3-Mercapto-2-butanol

Updated: 2026-07-15

Overview

3-Mercapto-2-butanol is an organosulfur compound with the molecular formula C4H8OS. It is characterized by the presence of a thiol (-SH) group, which imparts a strong sulfurous aroma. This compound is primarily used in the food and beverage industry as a flavoring agent, contributing meaty and roasted notes to products. Its synthesis typically involves the reaction of butenol with hydrogen sulfide or other sulfur-containing reagents. Due to its reactive nature, it is often handled in controlled environments to prevent oxidation or unwanted reactions. The compound's unique sensory properties make it valuable in creating complex flavor profiles.

Physical and Chemical Properties

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3-Mercapto-2-butanol is a colorless to pale yellow liquid with a density of approximately 1.03 g/cm³. It has a boiling point around 160-165°C and is soluble in alcohol but only slightly soluble in water. The thiol group is highly reactive, making the compound prone to oxidation, which can alter its odor profile. The compound's strong sulfurous odor is its most distinctive feature, often described as similar to garlic or onions at high concentrations. In diluted forms, it contributes desirable meaty or roasted nuances. Its reactivity requires careful handling and storage to maintain stability and prevent degradation.

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Main Applications

The primary use of 3-mercapto-2-butanol is as a flavoring agent in the food and beverage industry. It is particularly valued for its ability to enhance savory flavors, often used in meat products, snacks, and savory sauces. Its roasted aroma also makes it suitable for coffee and cocoa flavorings. Beyond flavors, it serves as a chemical intermediate in the synthesis of more complex sulfur-containing compounds. These intermediates may be used in pharmaceuticals or agrochemicals, though such applications are less common compared to its role in flavors and fragrances.

Safety and Storage

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3-Mercapto-2-butanol is classified as an irritant, particularly to skin and eyes. Proper personal protective equipment (PPE), including gloves and goggles, should be worn when handling the compound. Adequate ventilation is recommended to avoid inhalation of vapors. Storage should be in tightly sealed containers, away from light and oxidizing agents. Ideal conditions include cool, dry environments to prevent degradation. Shelf life can vary but is typically up to two years when stored correctly. Spills should be contained and cleaned promptly using appropriate absorbents.

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B2B Procurement Guide

When procuring 3-mercapto-2-butanol, buyers should prioritize suppliers who provide detailed certificates of analysis (CoA) to verify purity and composition. Food-grade specifications are critical if the compound is intended for flavoring applications. Pricing varies based on quantity and purity, with bulk purchases often offering cost advantages. Reliable suppliers should comply with Good Manufacturing Practices (GMP) and relevant food safety standards. Buyers may also inquire about packaging options, as smaller, sealed containers can help maintain product integrity for low-volume users. Lead times and shipping conditions (e.g., temperature control) should be confirmed to ensure quality upon delivery.

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