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2,4-Diaminobenzenesulfonic Acid

Updated: 2026-07-15

Overview

2,4-Diaminobenzenesulfonic acid is an aromatic organic compound that serves as a crucial building block in the synthesis of various dyes and pigments. As a bifunctional molecule containing both amino and sulfonic acid groups, it offers versatile reactivity for colorant production. The chemical is primarily manufactured through the sulfonation of m-phenylenediamine, followed by purification processes. Its importance in the dye industry stems from its ability to form stable diazo compounds and act as a coupling component in azo dye synthesis.

Physical and Chemical Properties

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This compound typically appears as a light brown to gray crystalline powder with limited solubility in cold water but good solubility in hot aqueous solutions. Its high melting point (above 300°C with decomposition) indicates thermal stability under normal processing conditions. The molecule's chemical behavior is dominated by its two amino groups (ortho and para to the sulfonic acid group), which participate in diazotization and azo coupling reactions. The sulfonic acid moiety enhances water solubility of derived dyes, making it particularly valuable for textile applications.

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Main Applications

Approximately 80% of global production is used in the manufacture of azo dyes for textiles, leather, and paper. The compound's amino groups enable formation of vivid, lightfast colors when coupled with appropriate diazonium salts. Secondary applications include production of hair dyes (particularly oxidative types), acid dyes for wool and silk, and as an intermediate for specialty pigments. Some pharmaceutical applications exist where it serves as a building block for certain sulfa drugs, though this represents a minor market segment.

Safety and Storage

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As an aromatic amine compound, proper handling precautions are essential. The powder can cause irritation to skin, eyes, and respiratory tract upon exposure. Appropriate PPE including gloves, goggles, and dust masks should be used during handling. Storage should be in tightly sealed containers away from strong oxidizers and heat sources. The material is generally stable under recommended storage conditions but may decompose if exposed to excessive moisture or temperatures above 50°C for prolonged periods.

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B2B Procurement Guide

Industrial buyers should prioritize suppliers with ISO certification and proper chemical handling documentation. Key specifications to verify include purity (typically 98-99%), heavy metal content (<10ppm), and moisture levels (<0.5%). Bulk shipments usually come in 25kg fiber drums or 500kg super sacks. Price negotiations often become favorable at multi-ton quantities. Consider regional producers in China, India, and Europe for competitive pricing, but always verify quality through certificates of analysis before large purchases.

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