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2-Hexanol

Updated: 2026-08-05

Overview

2-Hexanol is an organic compound belonging to the family of secondary alcohols. It is a six-carbon alcohol with the hydroxyl group on the second carbon atom. This chemical is primarily produced through the hydration of 1-hexene or as a byproduct in other chemical processes. As a moderately polar solvent, 2-hexanol finds use across various industries. Its balanced properties between volatility and solvency make it particularly valuable in formulations where a slower evaporation rate is desirable compared to lower molecular weight alcohols.

Physical and Chemical Properties

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2-Hexanol presents as a colorless liquid with a characteristic alcoholic odor. Its density of 0.81 g/cm³ makes it lighter than water. The compound shows limited water solubility (about 1.7 g/100 mL at 20°C) but is fully miscible with common organic solvents like ethanol, ether, and acetone. Chemically, 2-hexanol exhibits typical secondary alcohol reactivity. It can undergo oxidation to form ketones, participate in esterification reactions, and serve as a nucleophile in various synthesis pathways. The presence of the hydroxyl group allows for hydrogen bonding, influencing its solvent properties and boiling point.

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Main Applications

The primary use of 2-hexanol is as a solvent in industrial applications, particularly in coatings, inks, and cleaning formulations. Its moderate evaporation rate makes it suitable for products requiring extended open time, such as certain paint formulations. In chemical synthesis, 2-hexanol serves as an important intermediate. It's used in the production of plasticizers, particularly those based on phthalate esters. The pharmaceutical industry utilizes it in certain drug syntheses, while the fragrance industry values it for its solvent properties and as a precursor in aroma chemical production.

Safety and Storage

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As a flammable liquid (flash point about 45°C), 2-hexanol requires careful handling and storage. It should be kept in tightly sealed containers away from heat sources and oxidizing agents. Proper grounding is essential during transfer to prevent static discharge. From a health perspective, 2-hexanol may cause irritation upon contact with skin or eyes. Inhalation of vapors should be avoided, and adequate ventilation is necessary in work areas. Personal protective equipment including chemical-resistant gloves and safety goggles is recommended when handling this chemical.

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B2B Procurement Guide

Industrial buyers should specify purity requirements (typically 98% or higher for most applications) and preferred packaging options. Common commercial forms include 200L steel drums or bulk quantities in tank trucks for large-scale users. Quality certifications such as ISO or GMP compliance may be important for pharmaceutical-grade material. Lead times can vary from 2-6 weeks depending on quantity and location. It's advisable to request material safety data sheets (MSDS) and certificates of analysis from suppliers to ensure product quality meets application requirements.

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