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1,3,5-Trioxane

Updated: 2026-07-24

Overview

1,3,5-Trioxane is a cyclic organic compound consisting of three formaldehyde units. It is a stable, colorless solid with a faint odor, widely utilized in industrial and laboratory settings. The compound is particularly valued for its role as a solid fuel in military applications and as a precursor for formaldehyde-based resins. First synthesized in the 19th century, 1,3,5-trioxane has evolved into a versatile chemical intermediate. Its ability to release formaldehyde upon heating makes it useful in controlled-release applications, such as disinfection and polymer cross-linking.

Physical and Chemical Properties

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1,3,5-Trioxane crystallizes in a hexagonal structure, exhibiting a melting point of 62-64°C and sublimation at 115°C. Its density of 1.17 g/cm³ and solubility in polar solvents like water and ethanol facilitate its use in liquid formulations. The compound is thermally stable but decomposes upon heating to release formaldehyde. Key chemical properties include its reactivity as a formaldehyde donor, making it a substitute for gaseous or aqueous formaldehyde in industrial processes. It is incompatible with strong oxidizing agents and acids, which can accelerate decomposition.

Main Applications

The primary use of 1,3,5-trioxane is as a solid fuel in military and camping applications, where its clean combustion and high energy density are advantageous. It is also a key intermediate in producing polyoxymethylene (POM) plastics, known for their mechanical strength and dimensional stability. In laboratories, it serves as a stable formaldehyde source for organic synthesis. Additional applications include its use in adhesives, coatings, and as a cross-linking agent in resins. Its controlled-release properties are leveraged in disinfectants and preservatives.

Safety and Storage

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1,3,5-Trioxane is classified as a flammable solid (H228) and requires careful handling to prevent ignition. Storage should be in tightly sealed containers away from heat sources and open flames. Ventilated areas are recommended to avoid vapor accumulation. Personal protective equipment (PPE) such as gloves, goggles, and respirators should be used when handling the compound. Spills should be contained and cleaned promptly with inert absorbents. Regulatory guidelines, including OSHA and GHS, must be followed for workplace safety.

B2B Procurement Guide

Industrial buyers should prioritize suppliers with ISO or GMP certifications to ensure product consistency. Key procurement criteria include purity (≥99%), moisture content (<0.5%), and packaging integrity (typically 25 kg drums or custom quantities). Bulk pricing discounts are common for orders exceeding 1 metric ton. Buyers in the polymer industry should verify the compound’s compatibility with their specific resin formulations. Logistics planning must account for its flammability, requiring hazardous material transportation compliance.

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