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1-Octanethiol

Updated: 2026-07-17

Overview

1-Octanethiol, also known as octyl mercaptan, is an organic sulfur compound widely used in industrial applications. It belongs to the family of thiols, characterized by the presence of a sulfhydryl (-SH) group. Due to its strong odor and reactivity, it is primarily handled in controlled environments by professionals. This compound is synthesized through the reaction of 1-octanol with hydrogen sulfide or via other thiolation methods. Its versatility makes it valuable in chemical synthesis, particularly in the production of specialty chemicals and functional materials.

Physical and Chemical Properties

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1-Octanethiol is a colorless to pale yellow liquid with a pungent odor characteristic of thiols. It has a relatively low melting point of -49°C and a boiling point around 198-200°C. The compound is insoluble in water but dissolves readily in common organic solvents such as ethanol, ether, and benzene. Chemically, 1-octanethiol is reactive, particularly with oxidizing agents, and can form disulfides under certain conditions. Its flammability requires careful handling, and it should be stored away from heat and open flames to prevent combustion hazards.

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Main Applications

1-Octanethiol serves as a key intermediate in the synthesis of agrochemicals, pharmaceuticals, and specialty chemicals. Its ability to act as a corrosion inhibitor makes it useful in metal treatment processes, protecting surfaces from oxidative damage. In the polymer industry, it is employed as a chain transfer agent to control molecular weight during polymerization. Additionally, its strong odor has led to its use in odorant formulations for natural gas, helping detect leaks in pipelines.

Safety and Storage

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Due to its flammability and reactivity, 1-octanethiol must be handled with caution. Proper personal protective equipment (PPE), including gloves, goggles, and respirators, is essential to prevent skin contact, eye irritation, or inhalation of vapors. Storage should be in tightly sealed containers placed in a cool, dry, and well-ventilated area, away from oxidizing agents and heat sources. Spills should be contained and cleaned up immediately using appropriate absorbents to minimize environmental and health risks.

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B2B Procurement Guide

When procuring 1-octanethiol, buyers should specify the required purity level, as it can vary depending on the application. Common commercial grades range from 95% to 99% purity. Bulk purchases typically offer cost advantages, but storage capabilities must align with safety guidelines. Suppliers should provide material safety data sheets (MSDS) and certificates of analysis (CoA) to ensure compliance with regulatory standards. Buyers are advised to source from reputable manufacturers with a track record of quality and reliability.

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