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1-Dodecanethiol

Updated: 2026-07-15

Overview

1-Dodecanethiol, commonly referred to as lauryl mercaptan, is an organic sulfur compound widely used in industrial applications. It belongs to the family of alkylthiols and is known for its role as a chain transfer agent in polymerization processes. The compound is typically produced through the reaction of 1-dodecene with hydrogen sulfide. Due to its strong odor and flammability, 1-Dodecanethiol requires careful handling and storage. It is primarily utilized in the rubber and plastics industries, where it helps control molecular weight during polymerization. Its versatility and effectiveness make it a valuable chemical in various manufacturing processes.

Physical and Chemical Properties

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1-Dodecanethiol is a colorless to pale yellow liquid with a characteristic strong odor. It has a molecular weight of 202.40 g/mol and a density of 0.845 g/cm³ at 20°C. The compound is insoluble in water but dissolves readily in organic solvents such as ethanol and ether. With a melting point of -7°C and a boiling point ranging between 266-283°C, 1-Dodecanethiol is stable under normal conditions but can decompose when exposed to strong oxidizing agents. Its key chemical property is its ability to act as a chain transfer agent, which makes it essential in controlling polymer chain length during synthesis.

Main Applications

1-Dodecanethiol is predominantly used in the rubber and plastics industries. In rubber production, it serves as a vulcanization accelerator, enhancing the cross-linking of polymer chains to improve material properties. It is also employed as a chain transfer agent in the polymerization of styrene and other monomers, ensuring optimal molecular weight distribution. Additionally, 1-Dodecanethiol finds applications in the synthesis of surfactants and lubricant additives. Its ability to modify surface properties makes it useful in coatings and adhesives. The compound's versatility extends to the pharmaceutical and agrochemical sectors, where it is used as an intermediate in the synthesis of active ingredients.

Safety and Storage

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1-Dodecanethiol is classified as a hazardous substance due to its flammability and potential health risks. It can cause skin and eye irritation upon contact and is harmful if inhaled or ingested. Proper personal protective equipment (PPE), including gloves and goggles, should be worn when handling the chemical. Storage conditions for 1-Dodecanethiol require a cool, dry, and well-ventilated area, away from sources of ignition and oxidizing agents. Containers should be tightly sealed to prevent leaks and evaporation. In case of spills, absorbent materials should be used, and the area should be ventilated thoroughly to avoid inhalation exposure.

B2B Procurement Guide

When procuring 1-Dodecanethiol, B2B buyers should prioritize suppliers who provide detailed material safety data sheets (MSDS) and certificates of analysis (CoA). These documents ensure the chemical meets required purity and safety standards. Bulk purchases often come with cost advantages, but buyers should verify storage capabilities to maintain product integrity. Key considerations include packaging options (e.g., drums or totes) and transportation logistics, especially given the compound's flammability. Establishing long-term relationships with reputable suppliers can ensure consistent quality and reliable delivery schedules. Buyers should also stay informed about regulatory changes that may impact the availability or handling of 1-Dodecanethiol.

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